| Description |
1 online resource (xii, 296 pages) : illustrations |
| Series |
Oxford classic texts in the physical sciences |
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Oxford classic texts in the physical sciences.
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| Contents |
GLOSSARY OF NOTATION; 1. THE WATER MOLECULE; 1.1. The water molecule: description based on experiment; (a) Composition; (b) Energetics of formation; (c) Molecular dimensions; (d) Molecular vibrations; (e) Electrical properties; (f) Comparison of molecular energies; 1.2. The water molecule: description based on theory; (a) Electrostatic models; (b) Molecular orbital theory; (c) Electron density distribution; (d) Accurate wave functions and the calculation of physical properties; (e) The charge distribution: a summary; 2. THE REAL VAPOUR; 2.1. Forces between water molecules |
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(A) Origin and description of the forces(b) Virial coefficients; (c) Forces between water molecules: a summary; 2.2. Thermodynamic properties; (a) Pressure-volume-temperature relations; (b) Thermal energy; 3. ICE; 3.1. Structure of ice I; (a) Positions of the oxygen atoms; (b) Positions of the hydrogen atoms; (c) Amplitudes of thermal vibration; (d) Structure of ice I: a summary; 3.2. Structures of ice polymorphs; (a) Ices II, III, and V; (b) Ices VI, VII, and VIII; (c) Vitreous ice and ice Ic; (d) Structural characteristics of ice polymorphs: a summary; 3.3. Thermodynamic properties |
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(A) Phase relations(b) Thermal energy; (c) P-V-T data for ice I; 3.4. Electrical properties and self-diffusion; (a) Dielectric constant and dipole moment; (b) Dielectric polarization and relaxation; (c) Electrical conductivity; (d) Self-diffusion; 3.5. Spectroscopic properties; (a) Vibrational spectrum of ice I; (b) Vibrational spectra of ice polymorphs; (c) Nuclear magnetic resonance; 3.6. Hydrogen bonding; (a) Experimental energy of hydrogen bonding; (b) Potential functions for hydrogen-bonded molecules; (c) Theoretical description of the hydrogen bond in ice |
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(D) The properties of ice as determined by hydrogen bonds: a summary4. PROPERTIES OF LIQUID WATER; 4.1. Introduction; (a) Meaning of the term 'structure' as applied to liquid water; (b) Liquid structure and experimental techniques; 4.2. X-ray diffraction; (a) Radial distribution functions; (b) Interpretation of the radial distribution function in terms of V-structures; 4.3. Thermodynamic properties; (a) Thermal energy; (b) Pressure-volume-temperature relations; 4.4. Static dielectric constant and NMR chemical shift; (a) Static dielectric constant; (b) NMR chemical shift |
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4.5. Optical properties(a) Refractive index; (b) Light scattering; 4.6. Properties depending on the rates of molecular displacements; (a) Dielectric relaxation; (b) Relaxation of nuclear magnetism; (c) Self-diffusion; (d) Viscosity; (e) Ionic dissociation and migration; (f) Molecular displacements: a summary; 4.7. Vibrational spectroscopy; (a) Identification of spectral bands; (b) The O-H and O-D stretching bands; (c) Intramolecular vibrations; (d) Overtone and combination bands; 4.8. The structure of water: conclusions based on properties |
| Summary |
The authors have correlated many experimental observations and theoretical discussions from the scientific literature on water. Topics covered include the water molecule and forces between water molecules, the thermodynamic properties of steam, the structures of the ices, hydrogen bonding in ice and water and much more |
| Notes |
Originally published: Oxford: Clarendon, 1969 |
| Bibliography |
Includes bibliographical references (pages 271-282) and indexes |
| Notes |
English |
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Print version record |
| Subject |
Water.
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aquatic.
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water (inorganic material)
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SCIENCE -- Chemistry -- Inorganic.
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Water
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Water.
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Eigenschappen.
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Structuur.
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Stolling.
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Verdamping.
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Condensatie.
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Fotofysische eigenschappen.
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Elektrische geleiding.
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Viscositeit.
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| Form |
Electronic book
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| Author |
Kauzmann, Walter, 1916- author.
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| ISBN |
9780191524653 |
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0191524654 |
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9780198570264 |
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0198570260 |
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