Description |
1 online resource (467 pages) |
Series |
Monographs in Supramolecular Chemistry |
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Monographs in supramolecular chemistry.
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Contents |
880-01 Cover; Contents; Preface; Chapter 1 Applications of Synthetic Receptors for Biomolecules; 1.1 Biomolecule Recognition; 1.2 Types of Synthetic Receptors; 1.2.1 Small Organic Molecules; 1.2.2 Inorganic Molecules; 1.2.3 Synthetic Oligomers; 1.2.4 Molecular Imprinted Polymers; 1.2.5 Dendrimers; 1.2.6 Nanoparticles; 1.3 Common Applications; 1.3.1 Separations; 1.3.2 Imaging and Sensing; 1.3.3 Catalysis; 1.3.4 Pharmaceutical Activity; 1.4 Future Directions; 1.4.1 Logic Devices; 1.4.2 Biomolecule Responsive Materials; 1.4.3 Drug Delivery; 1.4.4 Biomolecule-fueled Molecular Machines; Acknowledgments |
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880-01/(S 3.8 Ammonium Cations and Structural Effects3.9 Photoresponsive Receptors; 3.9.1 Detecting Complexation Colorimetrically; 3.9.2 Detecting Complexation Fluorometrically; 3.10 Cation Transport; 3.10.1 Design of a Dynamic Cation Carrier; 3.10.2 Lariat Ethers; 3.10.3 Cation-π Interactions with Alkali Metal Cations; 3.11 Salt Complexation: Ditopic Receptors; 3.12 Pore-forming Amphiphiles; 3.12.1 A Cyclodextrin-based Channel; 3.12.2 Synthetic Amphiphilic Ionophores: Synthetic Ion Channels; 3.12.3 Hydraphile Biological Activity; 3.13 Future Challenges; References |
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2.7 Synthetic Receptors Derived from Combinatorial Techniques2.8 Dynamic Combinatorial Libraries for Receptor Discovery; 2.9 Cooperativity; 2.10 Entropy-Enthalpy Compensation; 2.11 Cross-reactive Arrays; 2.12 Conclusion; References; Chapter 3 Synthetic Receptors for Alkali Metal Cations; 3.1 Complexation of Alkali Metal Cations; 3.1.1 Coordination Complexes, Receptors, and Dynamics; 3.2 The Forces Involved in Complexation; 3.2.1 Enthalpy-Entropy Compensation; 3.2.2 Drawing Structural Conclusions from Binding Constants; 3.3 A Brief Overview of Complexation Constants |
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3.4 The Dynamics of the Complexation Process3.4.1 Solvent Effect on Complexation; 3.5 Crown Ethers and Related Receptor Types; 3.5.1 Crown Ethers; 3.5.2 Cryptands; 3.5.3 Spherands; 3.5.4 Calixarenes, Cavitands, and Other Complexing Agents; 3.6 Assessing Complexation; 3.6.1 Calorimetry; 3.6.2 Ion-selective Electrode Studies; 3.6.3 Salt Extraction and Colorimetry; 3.6.4 Comparison of Binding Assays; 3.6.5 Bulk Membrane Transport Rates; 3.6.6 Liposomal Membrane Studies; 3.7 Controlling Transport and Molecular Switching; 3.7.1 Redox Switching; 3.7.2 Photo-switched Transport |
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Chapter 4 Synthetic Receptors for Small Organic and Inorganic Anions |
Summary |
An accessible overview of the most effective synthetic receptors within the context of specific applications |
Bibliography |
ReferencesChapter 2 Design and Synthesis of Synthetic Receptors for Biomolecule Recognition; 2.1 The Foundations of Host-Guest Chemistry: Preorganization and Complementarity; 2.2 Strengths of Molecular Recognition Interactions; 2.3 Solvent Dependence of Binding Interactions; 2.4 Reversible Covalent Bonding; 2.5 From Plastic Models to Modern Computational Methods; 2.6 Common Synthetic Receptor Scaffolds; 2.6.1 Crown Ethers; 2.6.2 Calix[n]arenes; 2.6.3 Calix[n]pyrroles; 2.6.4 Cucurbit[n]urils; 2.6.5 Cyclodextrins; 2.6.6 Pinwheel Scaffolds |
Notes |
English |
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Print version record |
Subject |
Cell receptors -- Synthesis
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Protein engineering.
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Biomolecules.
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Supramolecular chemistry.
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Cell receptors.
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Mathematical models.
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Membrane proteins.
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Proteins.
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Models, Molecular
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Receptors, Cell Surface
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Models, Theoretical
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Membrane Proteins
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Investigative Techniques
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Proteins
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Analytical, Diagnostic and Therapeutic Techniques and Equipment
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Amino Acids, Peptides, and Proteins
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Chemicals and Drugs
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Protein Engineering
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mathematical models.
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protein.
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Biochemistry.
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SCIENCE -- Life Sciences -- Biochemistry.
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SCIENCE -- Chemistry -- General.
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Supramolecular chemistry.
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Biomolecules.
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Protein engineering.
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Form |
Electronic book
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Author |
Anslyn, Eric
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Gokel, George
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Kubik, S
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Wang, Binghe
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Smith, Bradley D
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Hong, Jong-In
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Hargrove, A. E
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Schmuck, C
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Rotello, David
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Royal Society of Chemistry (Great Britain), Content Provider.
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ISBN |
1849739714 |
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9781849739719 |
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9781782622062 |
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1782622063 |
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