| Description |
1 online resource (xx, 1154 pages) |
| Contents |
Volume 1 ; Preface to the Third Edition xiii ; Preface to the Second Edition xv ; Preface to the First Edition xvii ; Introduction xix ; Introduction and General Aspects 1 ; 1.1 Hydrocarbons and Their Classes 1 ; 1.2 EnergyHydrocarbon Relationships 2 ; 1.3 Hydrocarbon Sources 4 ; Extraterrestrial Hydrocarbons 15 ; 1.4 Hydrocarbon Production from Natural Sources 16 ; 1.5 Hydrocarbon Synthesis 20 ; 1.6 Nonrenewable and Renewable Hydrocarbons 27 ; 1.7 Regenerative Hydrocarbons from CO2 Emission Capture and Recycling 29 ; 1.8 Hydrocarbon Functionalization Reactions 30 ; 1.9 Use of Hydrocarbons, Petroleum Oil 35 ; 1.9.1 Energy Generation, Storage, and Delivery: Heating 36 ; 1.9.2 Transportation Fuels 36 ; 1.9.3 Chemical Products, Plastics, and Pharmaceuticals 38 ; References 38 ; Hydrocarbons from Petroleum and Natural Gas 49 ; 2.1 Cracking 49 ; 2.2 Reforming 62 ; Hydroforming 64 ; Metal-Catalyzed Reforming 65 ; 2.3 Dehydrogenation with Olefin Production 71 ; Heterogeneous Catalysts 73 ; Homogeneous Catalysts 78 ; C2C3 Alkenes 85 ; C4 Alkenes 86 ; Buta-1,3-diene and Isoprene 87 ; Higher Olefins 88 ; Styrene 88 ; 2.4 Upgrading of Natural-Gas Liquids 89 ; 2.5 Aromatics Production 89 ; References 102 ; Synthesis from C Sources 125 ; 3.1 Aspects of C1 Chemistry 126 ; 3.2 Chemical Reduction to Methanol and Oxygenates; Recycling of CO2 127 ; Heterogeneous Hydrogenation 129 ; Homogeneous Hydrogenation 137 ; Ionic Reduction 143 ; Electrochemical and Electrocatalytic Reduction 143 ; Photoreduction 146 ; Enzymatic Reduction 148 ; 3.3 FischerTropsch Chemistry 149 ; 3.4 Oxygenation of Methane 166 ; Methanol Synthesis 166 ; 3.5 Oligocondensation of Methane 173 ; 3.6 Hydrocarbons from Methane Derivatives 186 ; Methanol Conversion to Hydrocarbons 186 ; Methanol to Hydrocarbon Technologies 196 ; Methanol to Gasoline 196 ; Methanol to Olefin 197 ; Methanol to Propylene 198 ; References 200 ; Isomerization 237 ; 4.1 Acid-Catalyzed and Bifunctional Isomerization 238 ; Mechanism 243 ; Side-Chain Isomerization 250 ; Positional Isomerization 250 ; 4.2 Base-Catalyzed Isomerization 262 ; 4.2.1 Alkenes 262 ; 4.3 Metal-Catalyzed Isomerization 266 ; 4.4 Pericyclic Rearrangements 277 ; 4.5 Practical Applications 284 ; Alkanes 284 ; Alkenes 285 ; 4.5.2 Isomerization of Xylenes 286 ; References 287 ; Alkylations 305 ; 5.1 Acid-Catalyzed Alkylation 305 ; Alkylolysis (Alkylative Cleavage) 317 ; Alkylation of Alkenes with Organic Halides 318 ; Alkylation of Alkynes 320 ; Alkylation with Carbonyl Compounds: The Prins Reaction 320 ; Catalysts 324 ; Alkylation with Alkyl Halides 326 ; Alkylation with Alkenes 331 ; Alkylation with Alkanes 335 ; Alkylation with Other Reagents 338 ; 5.2 Base-Catalyzed Alkylation 350 ; 5.3 Alkylation through Organometallics 352 ; 5.4 Miscellaneous Alkylations 356 ; 5.5 Practical Applications 360 ; References 369 ; Addition Reactions 389 ; 6.1 Hydration 389 ; Production of Alcohols by Hydration of Alkenes 395 ; Production of Octane-Enhancing Oxygenates 396 ; Acetaldehyde 397 ; 6.2 HX Addition 398 ; Alkenes 398 ; Dienes 403 ; Alkynes 404 ; Ethyl Chloride 411 ; Hydrochlorination of Buta-1,3-diene 411 ; Vinyl Chloride 411 ; Ethylene Chlorohydrin 412 ; Propylene Chlorohydrin 412 ; Adiponitrile 412 ; Acrylonitrile 413 ; 6.3 Halogen Addition 413 ; Vinyl Chloride 422 ; Chlorination of Buta-1,3-diene 424 ; 6.4 Addition to Form CN Bonds 424 ; 6.5 Addition to Form CO, CS, and CP Bonds 433 ; 6.6 Hydrometalation 439 ; Alkenes 440 ; Dienes 446 ; Alkynes 448 ; Alkenes 452 ; Dienes 456 ; Alkynes 457 ; 6.7 Halometalation 462 ; 6.8 Solvometalation 465 ; 6.9 Carbometalation 466 ; 6.10 Cycloaddition 471 ; References 477 ; Carbonylation and Carboxylation 509 ; 7.1 Carbonylation 509 ; Hydroformylation in Biphasic Solvent Systems 515 ; The Use of Heterogeneous Catalysts 516 ; Hydroformylation of Higher Alkenes 518 ; Hydroformylation of Internal Alkenes 519 ; Asymmetric Hydroformylation 520 ; 7.2 Carboxylation 533 ; Saturated Hydrocarbons 534 ; Aromatic Hydrocarbons 536 ; Hydrocarboxylation and hydroesterification 539 ; Aminocarboxylation 545 ; Neocarboxylic Acids 547 ; Hydrocarboxymethylation of Long-Chain Alkenes 547 ; Propionic Acid 547 ; Acrylic Acid and Acrylates 548 ; References 548 ; Acylation 569 ; 8.1 Acylation of Aromatics 569 ; New Soluble Catalysts 573 ; Solid Catalysts 575 ; The GattermannKoch Reaction 577 ; The Gattermann Reaction 579 ; Other Formylations 580 ; 8.2 Acylation of Aliphatic Compounds 581 ; References 586 ; Index 000 ; Volume 2 ; Preface to the Third Edition xi ; Preface to the Second Edition xiii ; Preface to the First Edition xv ; Introduction xvii ; OxidationOxygenation 593 ; 9.1 Oxidation of Alkanes 594 ; Autoxidation of Alkanes 594 ; Oxidation of Methane 596 ; Oxidation with Stoichiometric Oxidants 606 ; Oxidation Catalyzed by Enzymes and Metalloporphyrins 613 ; Metal-Catalyzed Oxidation in the Homogeneous Phase 616 ; Oxidation Induced by Heterogeneous Catalysts 619 ; Metal Oxidants 623 ; Electrophilic Reagents 624 ; Oxygenolysis 628 ; 9.2 Oxidation of Alkenes 630 ; Direct Oxidation with Stoichiometric Oxidants 630 ; Metal-Catalyzed Epoxidation 635 ; Epoxidation Catalyzed by Metalloporphyrins 644 ; Asymmetric Epoxidation 647 ; Autoxidation 650 ; Reactions with Singlet Oxygen 650 ; Bis-Hydroxylation 656 ; Bis-Acetoxylation 663 ; Oxidation with Palladium in the Homogeneous Phase 664 ; Oxidation with Other Reagents 669 ; Vinylic Acetoxylation 671 ; Ozonation 673 ; Mechanism 673 ; Synthetic Applications 676 ; Other Oxidants 678 ; Allylic Hydroxylation and Acyloxylation 681 ; Oxidation to a, b-Unsaturated Carbonyl Compounds 686 ; 9.3 Oxidation of Alkynes 690 ; 9.4 Oxidation of Aromatics 693 ; Oxidation to Phenols 693 ; Ring Acyloxylation 701 ; Oxidation to Quinones 702 ; Oxidation to Arene Oxides and Arene Diols 703 ; Oxidation with Singlet Oxygen 704 ; Oxidation of Methyl-Substituted Aromatics 706 ; Oxidation of Other Arenes 708 ; Benzylic Acetoxylation 711 ; 9.5 Practical Applications 712 ; Acetic Acid 712 ; Maleic Anhydride 713 ; Oxidation of Cyclohexane 715 ; Oxidation of Cyclododecane 715 ; sec-Alcohols 715 ; Ethylene Oxide 716 ; Propylene Oxide 718 ; Acetaldehyde and Acetone 719 ; Vinyl Acetate 719 ; 1,4-Diacetoxybut-2-ene 720 ; Acrolein and Acrylic Acid 720 ; Methacrolein and Methacrylic Acid 721 |
| Summary |
"This book provides an unparalleled contemporary assessment of hydrocarbon chemistry - presenting basic concepts, current research, and future applications"-- Provided by publisher |
| Notes |
Volume 1 |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Online resource; title from digital title page (viewed on November 07, 2017) |
| Subject |
Hydrocarbons.
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SCIENCE -- Chemistry -- Organic.
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SCIENCE -- Chemistry -- Industrial & Technical.
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TECHNOLOGY & ENGINEERING -- Petroleum.
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Hydrocarbons
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| Form |
Electronic book
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| Author |
Molnár, Árpád, 1942- author.
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Prakash, G. K. Surya, author
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| LC no. |
2017023298 |
| ISBN |
9781119390527 |
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1119390524 |
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9781119390541 |
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1119390540 |
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9781523123612 |
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1523123613 |
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