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Author Lechner, Barbara A. J., author

Title Studying complex surface dynamical systems using helium-3 spin-echo spectroscopy / Barbara A.J. Lechner
Published Cham : Springer, 2014

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Description 1 online resource
Series Springer theses
Springer theses.
Contents Motivation -- The helium-3 spin-echo experiment -- A new helium atom scattering apparatus -- An improved high intensity supersonic helium beam source -- The dynamics of cyclopentadienyl on Cu(111) -- Quantum influences in the diffusive motion of pyrrole on Cu(111) -- The diffusive motion of thiophene on Cu(111) -- Conclusions
Summary Chemical reactions and growth processes on surfaces depend on the diffusion and re-orientation of the adsorbate molecules. A fundamental understanding of the forces guiding surface motion is thus of utmost importance for the advancement of many fields of science and technology. To date, our understanding of the principles underlying surface dynamics remains extremely limited, due to the difficulties involved in measuring these processes experimentally. The helium-3 spin-echo (HeSE) technique is uniquely capable of probing such surface dynamical phenomena. The present thesis extends the field of application of HeSE from atomic and small molecular systems to more complex systems. Improvements to the supersonic helium beam source, a key component of the spectrometer, as well as a detailed investigation of a range of five-membered aromatic adsorbate species are presented. The thesis provides a comprehensive description of many aspects of the HeSE method - instrumentation, measurement and data analysis - and as such offers a valuable introduction for newcomers to the field
Notes "Doctoral thesis accepted by the University of Cambridge, Cambridge, UK."
Bibliography Includes bibliographical references
Notes English
Print version record
In Springer eBooks
Subject Surfaces (Physics)
Electron paramagnetic resonance spectroscopy.
Electron Spin Resonance Spectroscopy
SCIENCE -- Energy.
SCIENCE -- Mechanics -- General.
SCIENCE -- Physics -- General.
Physique.
Astronomie.
Electron paramagnetic resonance spectroscopy
Surfaces (Physics)
physics.
physical chemistry.
measuring.
Form Electronic book
ISBN 9783319011806
3319011804
3319011790
9783319011790