| Description |
1 online resource (viii, 339 pages) : illustrations |
| Series |
Topics in organometallic chemistry, 1436-6002 ; v. 19 |
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Topics in organometallic chemistry ; 19.
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| Contents |
Palladium-catalyzed cyclization via carbopalladation and acylpalladation / E. Negishi, G. Wang and G. Zhu -- Domino Heck-pericyclic reactions / P. von Zezschwitz and A. deMeijere -- Palladium catalyzed cascade reactions involving pi-allyl palladium chemistry / N.T. Patil and Y. Yamamoto -- The virtue of Michael-type addition processes in the design of transition metal-promoted cyclizative cascade reactions / G. Balme, D. Bouyssi and N. Monteiro -- Sequentially palladium-catalyzed processes / T.J.J. Müller -- Cascade reactions involving Pauson-Khand and related processes / J. Pérez-Castells -- Complex polycyclic molecules from acyclic precursors via transition metal-catalyzed cascade reactions / C. Aubert, L. Fensterbank, V. Gandon and M. Malacria -- Cascade and sequential catalytic transformations initiated by ruthenium catalysts / C. Bruneau, S. Dérien and P.H. Dixneuf |
| Summary |
Transition metal-catalyzed cascade reactions are an elegant approach to complex molecular scaffolds. Besides their esthetics and increase in structural complexity, they have also become mechanistic challenges for the combination of organometallic elementary steps. As a consequence, cascade reactions have revolutionized synthetic strategies and conceptual thinking. The authors highlight cyclization via carbopalladation and acylpalladation and Heck-pericyclic sequences. They discuss p-allyl palladium-based cascade reactions, Michael-type additions as an entry to transition-metal-promoted cyclizative transformations, and sequential or consecutive palladium-catalyzed processes, and show Pauson-Khand cascades, metal-catalyzed cyclizations of acyclic precursors, as well as cascade and sequential ruthenium-catalyzed transformations. Therefore, the reader finds overview of an exciting and highly dynamic field of a new and innovative methodological concept |
| Analysis |
chemie |
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chemistry |
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organometaalverbindingen |
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organometallic compounds |
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katalyse |
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catalysis |
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anorganische scheikunde |
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inorganic chemistry |
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Chemistry (General) |
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Chemie (algemeen) |
| Bibliography |
Includes bibliographical references and indexes |
| Notes |
English |
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Current copyright fee: GBP19.00 42\0. Uk |
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Print version record |
| In |
Springer e-books |
| Subject |
Transition metal catalysts.
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Organometallic chemistry.
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Transition metal catalysts.
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Organometallic chemistry.
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Chimie.
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Science des matériaux.
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Organometallic chemistry
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Transition metal catalysts
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| Form |
Electronic book
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| Author |
Müller, Thomas J. J
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Aubert, C. (Corinne)
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| ISBN |
9783540329596 |
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3540329595 |
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3540329587 |
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9783540329589 |
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