| Description |
1 online resource (x, 305 pages) : illustrations (some color) |
| Series |
Springer series in materials science, 0933-033X ; 138 |
|
Springer series in materials science ; v. 138.
|
| Contents |
Cover13; -- Macromolecular Metal Carboxylates and Their Nanocomposites -- Preface13; -- Contents13; -- Chapter 1 Introduction -- References -- Chapter 2 Monomeric and Polymeric Carboxylic Acids -- 2.1 Mono- and Polybasic Unsaturated Carboxylic Acids: Characteristic and Polymerization -- 2.1.1 Monobasic Carboxylic Acids with One Double Bond -- 2.1.2 Unsaturated Dicarboxylic (Dibasic) Acids -- 2.1.3 Unsaturated Carboxylic Acids with Triple Bond (Acetylenic Acids) -- 2.2 Peculiarity of Polymerization of Unsaturated Carboxylic Acids and their Polymers Structure -- 2.3 Stereoregular Polyacids -- 2.4 Cross-Linked Polyacids -- 2.5 Graft- and Block-Copolymers with Carboxyl Fragments -- 2.6 Natural Polyacids -- 2.6.1 Polysaccharides -- 2.6.2 Humic Acids -- References -- Chapter 3 Synthesis of Unsaturated Carboxylic Acid Salts -- 3.1 Reaction of Unsaturated Carboxylic Acids with Metal Hydroxides, Oxides, and Carbonates -- 3.2 Reactions of Acetates and Other Salts with Unsaturated Carboxylic Acids -- 3.3 Ligand Exchange Reactions -- 3.3.1 With Metal Halides -- 3.3.2 With Metal Alkoxides -- 3.3.3 Other Exchange Reactions -- 3.3.4 Synthesis of Bimetallic Compounds -- 3.4 Sol8211;Gel Reactions -- 3.5 Other Reactions -- 3.6 Synthesis of Cluster Containing Unsaturated Carboxylates -- References -- Chapter 4 Spectral Characteristics and Molecular Structureof Unsaturated Carboxylic Acid Salts -- 4.1 Metal (Meth)acrylates -- 4.1.1 IR Spectroscopy -- 4.1.2 Magnetic Properties -- 4.1.3 Electron Spectroscopy -- 4.1.4 Molecular Structure -- 4.2 Metal Dicarboxylates -- 4.2.1 Monomeric Salts -- 4.2.2 Coordination Polymers -- 4.2.3 Ferromagnetic Properties of Metal Dicarboxylates -- 4.3 -Complexes of Metal Carboxylates -- 4.4 Unsaturated -Oxo Multinuclear Metal Carboxylates -- 4.4.1 IR-Spectroscopy -- 4.4.2 Mass-Spectrometry -- 4.4.3 Molecular Structure -- 4.5 Cluster-Containing Unsaturated Carboxylates -- 4.6 Metal Carboxylates with Unsaturated Ligands of Acetylene Type -- References -- Chapter 5 Polymerization and Copolymerization of Salts of Unsaturated Carboxylic Acids -- 5.1 Types of Initiation -- 5.2 Kinetic and Stereochemical Effects -- 5.2.1 Radical Polymerization of Alkali and Alkaline Earth Metal Salts of Unsaturated Carboxylic Acids -- 5.2.2 Radical Polymerization of TransitionMetal (Meth)acrylates -- 5.2.3 Regulation of Stereochemistry of Radical Polymerization of Metal Carboxylates -- 5.3 Solid Phase Polymerization of Unsaturated Metal Carboxylates -- 5.3.1 Thermal Polymerization of Unsaturated Metal Carboxylates -- 5.3.2 Solid State UV and Radiation Initiated Polymerization -- 5.3.3 Reactivity of Unsaturated Metal Carboxylatesin Solid Phase -- 5.4 Copolymerization and Terpolymerization -- 5.4.1 The Main Principles of Copolymerizationof Alkali and Alkaline Earth Metal Salts -- 5.4.2 Reactivity of Tin-Containing Carboxylates -- 5.4.3 Copolymerization of Transition Metal Salts -- 5.4.4 Kinetic Features -- 5.4.5 Terpolymerization -- References -- Chapter 6 Polymer-Analog Transformations in Reactionsof Synthesis of Metal Macrocarboxylates -- 6.1 Complexation of Metal Ions with Macromolecular Ligands -- 6.2 Metal Ion Binding by Polyacids -- 6.3 Metal Ion Binding by Stereoregular Polyacids -- 6.4 Peculiarities of MXn Binding by Cross-Linked Polyacids -- 6.5 Formation of Macrocomplexes with Grafted Polycarboxylic Fragments -- 6.6 Bimetallic Polycomplexes -- T$298 |
| Summary |
Data on the synthesis and physicochemical studies of salts of mono- or dibasic unsaturated carboxylic acids and macromolecular metal carboxylates are generalised and described systematically. The structures and properties of the COO group in various compounds and characteristic features of the structures of carboxylate are analysed. The main routes and kinetics of polymerisation transformations of unsaturated metal carboxylates are considered. The attention is focused on the effect of the metal ion on the monomer reactivity and the polymer morphology and structure. The possibility of stereochemical control of radical polymerisation of unsaturated metal carboxylates is demonstrated. The electronic, magnetic, optical, absorption and thermal properties of metal (co)polymers and nanocomposites and their main applications are considered |
| Bibliography |
Includes bibliographical references and index |
| Subject |
Metallic soaps.
|
|
Macromolecules.
|
|
Nanocomposites (Materials)
|
|
Nanocomposites
|
|
TECHNOLOGY & ENGINEERING -- Chemical & Biochemical.
|
|
Physique.
|
|
Macromolecules
|
|
Metallic soaps
|
|
Nanocomposites (Materials)
|
|
Metallorganische Polymere
|
|
Carboxylate
|
| Form |
Electronic book
|
| Author |
Dzhardimalieva, G. I. (Gulʹzhian Iskakovna)
|
|
Kestelʹman, V. N. (Vladimir Nikolaevich)
|
| ISBN |
9783642105746 |
|
3642105742 |
|
