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Author Prud'homme, Roger.

Title Flows and Chemical Reactions in Homogeneous Mixtures / Roger Prud'homme
Published London : ISTE ; Hoboken : Wiley, ©2013

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Description 1 online resource (xxiv, 223 pages) : illustrations
Series Fluid mechanics series
Fluid mechanics series.
Contents Machine generated contents note: ch. 1 Flows in Nozzles -- 1.1. Sound propagation in the presence of chemical reactions -- 1.1.1. Thermodynamic considerations -- 1.1.2. Sound propagation in a mono-reactive medium -- 1.1.3. Sound propagation in a multi-reactive medium -- 1.2. Relaxed flows in nozzles -- 1.2.1. Calculation of a continuous flow with a recombination-dissociation reaction in a de Laval nozzle -- 1.2.2. Asymptotic study of the transonic zone of a continuous mono-dimensional flow in a de Laval nozzle -- 1.3. Flows in thermal and chemical non-equilibrium -- 1.3.1. Balance equations and closure relations in the presence of thermal and chemical non-equilibria -- 1.3.2. Application -- 1.4. Conclusion about flows in nozzles -- ch. 2 Chemical Reactors -- 2.1. Ideal reactors, real reactors, balance equations -- 2.1.1. Ideal chemical reactors -- 2.1.2. Balance equations for chemical reactors -- 2.2. Perfectly mixed homogeneous chemical reactors -- 2.2.1. Equations for a perfectly stirred homogeneous chemical reactor -- 2.2.2. Steady regimes in perfectly stirred homogeneous chemical reactors -- 2.2.3. Stability of operating points in the perfectly stirred homogeneous chemical reactor -- 2.3. Tubular reactor -- 2.3.1. Plug flow reactor -- 2.3.2. Reactor with axial mixing -- 2.3.3. Reactor with radial mixing -- 2.4. Residence time distribution -- 2.4.1. Balance equations -- 2.4.2. Perfectly stirred homogeneous reactors in a steady regime -- 2.4.3. Plug flow reactors -- 2.4.4. Poiseuille flow -- 2.4.5. Real reactors -- ch. 3 Laminar and Turbulent Flames -- 3.1. Laminar premixed combustion -- 3.1.1. Rankine-Hugoniot theory -- 3.1.2. Velocity and structure of the plane adiabatic laminar and steady premixed flame -- 3.1.3. Other examples of a steady laminar premixed flame -- 3.2. Laminar non-premixed combustion -- 3.2.1. Burke -- Schumann problem -- 3.2.2. Other examples of diffusion flames -- 3.3. Turbulent combustion -- 3.3.1. Averaged balance equation for turbulent combustion -- 3.3.2. Premixed turbulent combustion regimes -- 3.3.3. Non-premixed turbulent combustion regimes -- 3.3.4. Models of turbulent combustion -- 3.3.5. LESs in combustion -- 3.3.6. Triple flames -- Appendices -- Appendix 1 Dimensionless Numbers, Similarity -- A1.1. Fundamentals of dimensional analysis: ?i groups -- A1.1.1. Basic considerations -- A1.1.2. Vaschy -- Buckingham theorem (1890) or ? theorem -- A1.1.3. Practical advantage to dimensional analysis -- A1.1.4. Example of application: head loss in a cylindrical pipe -- A1.2. Similarity -- A1.2.1. Definition -- A1.2.2. Application: condition of similarity in a soft balloon placed in a current of air with a given velocity -- A1.3. Analytical searching for solutions to a heat transfer problem (self-similar solution) -- A1.4. Some dimensionless numbers -- Appendix 2 Thermodynamic Functions -- A2.1. General points -- A2.2. Translational motion -- A2.3. Internal motions -- A2.3.1. Monatomic species -- A2.3.2. Diatomic species -- A.2.3.3. Linear polyatomic species -- A2.3.4. Nonlinear polyatomic species -- Appendix 3 Concepts of Turbulence -- A3.1. Experimental demonstration -- A3.1.1. Reynolds' experiment -- A3.1.2. Viscous flow over a smooth plane plate -- A3.1.3. Effect of roughness of the plate -- A3.1.4. Effect of turbulence on chemical reactivity -- A3.2. Apparition and damping of turbulence -- A3.2.1. Instability between two superposed fluids -- A3.2.2. Instability of a fluid between two rotating cylinders -- A3.2.3. Instability of a premixed flame -- A3.2.4. Damping of turbulence -- A3.3. Classic turbulence (RANS model) -- A3.3.1. Turbulent transfer and chemical kinetics coefficients -- A3.3.2. Remarks about averages and scales -- A3.3.3. k -- ? models (closure for transfer terms) -- A3.3.4. Spectral analysis and Kolmogorov's theory -- A3.4. Ideas about large eddy simulation -- A3.4.1. Filtering -- A3.4.2. Filtered balance equations for a non-reactive incompressible fluid -- A3.4.3. Closure relations for the filtered balance equations -- A3.5. Conclusion -- Appendix 4 Thermodynamic functions for a mixture in disequilibrium -- A4.1. Thermodynamics -- A4.2. Chemistry
Summary Flows with chemical reactions can occur in various fields such as combustion, process engineering, aeronautics, the atmospheric environment and aquatics. /The examples of application chosen in this book mainly concern homogeneous reactive mixtures that can occur in propellers within the fields of process engineering and combustion: /' propagation of sound and monodimensional flows in nozzles, which may include disequilibria of the internal modes of the energy of molecules; /' ideal chemical reactors, stabilization of their steady operation points in the homogeneous case of a perfect mixture and classical instruments of experimental and theoretical analysis such as population balances, and the distribution of residence and passage times; /' laminar and turbulent flames, separating those which are premixed from those which are not and which do not exhibit the same mechanisms, but which also occur in the case of triple flames. /Flows and Chemical Reactions in Homogeneous Mixtures provides information on dimensional analysis, statistical thermodynamics with coupling between internal modes and chemical reactions, the apparition and damping of fluid turbulence as well as its statistical processing, bifurcations, flames in a confined medium and diffusion. / Contents/ 1. Flows in Nozzles. /2. Chemical Reactors. /3. Laminar and Turbulent Flames. /Appendix 1. Dimensionless Numbers, Similarity. /Appendix 2. Thermodynamic Functions. /Appendix 3. Concepts of Turbulence. /Appendix 4. Thermodynamic functions for a mixture in disequilibrium. /Appendix 5. Notion of bifurcation. /Appendix 6. Confined flame. /Appendix 7. Limits of Validity of the First-order Expansions for Diffusion Flames./ About the Authors/ Roger Prud'homme has been Emeritus Research Director at CNRS, in France, since 2004. His most recent research topics have included flames (premixed flame modeling and their behavior in microgravity), two phase flows (droplet combustion with condensation of the products, sound propagation in suspensions, vortex, chock wave structure) and the modeling of fluid interfaces. He has published 5 books, 7 contributions to volumes and 50 publications in international journals
Bibliography Includes bibliographical references (pages 207-217) and index
Notes Online resource; title from PDF title page (Wiley, viewed Nov. 5, 2013)
Subject Fluid dynamics -- Mathematical models
Chemical reactions.
SCIENCE -- Mechanics -- General.
Chemical reactions
Fluid dynamics -- Mathematical models
Form Electronic book
LC no. 2013945046
ISBN 9781118832653
1118832655
9781299966253
129996625X
9781118832660
1118832663
1848216335
9781848216334
1118832620
9781118832622