| Description |
1 online resource |
| Contents |
Cover; Title Page; Copyright Page; Half Title; Table of Contents; PREFACE; I: BASICS OF PULSE AND FOURIER TRANSFORM NMR; A. Introduction; B. The rotating frame; C. Pulse NMR; 1. Introduction to pulse NMR; 2. Pulse NMR experiments; D. Introduction to Fourier transform NMR; 1. The driven vs. the pulsed simple harmonic oscillator: An introduction to Fourier transform pairs; 2. The nature of Fourier transform NMR; 3. Comparison of FT and cw NMR; II: DETAILS OF PULSE AND FOURIER TRANSFORM NMR; A. Fundamentals; 1. Some useful Fourier transform theorems |
|
2. Pulse length, tip angle, and all that (or just what is the rf pulse doing to the magnetization?3. Quadrature detection; B. The mechanics of FT NMR; 1. Digitizing rate and the size of the transform; 2. Dynamic range and digitizer resolution; 3. Positioning the carrier; 4. Phase correction; 5. Digitally massaging the FID; 6. FT spectroscopy of wide lines; C. Decoupling in Solution NMR; Broadband heteronuclear decoupling; selective and off-resonance heteronuclear decoupling; gated decoupling; homonuclear decoupling; Decoupling power; D. Special topics |
|
1. Pulse response in the presence of quadrupole splitting2. Selective excitation; 3. 2-D spectroscopy; 4. CPMG J-spectra; 5. Echoes in liquids; III: RELAXATION; A. General remarks; What is spin-lattice relaxation?; How does spin-lattice relaxation take place?; Other kinds of nuclear relaxation; The spectral density; Additional Observations; B. Spin-spin relaxation; C. Spin-lattice relaxation; 1. Spin-lattice relaxation mechanisms; 2. How to differentiate between mechanisms; 3. Relaxation of quadrupolar nuclei; 4. Oxygen removal from samples; D. Measurement of spin-lattice relaxation |
|
1. Strategies2. Some typical pulse sequences for T1 measurements; Double pulse; Steady state sequence; Progressive saturation with inversion recovery; Saturating comb; 3. T1 measurements in high resolution NMR; 4. Long T1 problems; 5. Analysis of exponential time constants; E. Molecular diffusion in a field gradient; 1. Diffusion in a steady field gradient; 2. Pulse field gradient method; Stejskal and Tanner sequence; potential problems with pulsed gradient method; Lowe and Karlicek method; stimulated echo method; restricted diffusion; 3. Gradient calibration; IV: NMR OF SOLIDS |
|
A. Lineshapes in solids1. Homogeneous and inhomogeneous lines; 2. Moments of absorption lines; B. Dipolar and Zeeman order; 1. The meaning of dipolar and Zeeman order; 2. Rotating frame adiabatic demagnetization; 3. The solid echo and other two pulse echoes; 4. The Jeener echo; C. Rotating frame relaxation; 1. Rotating frame spin-lattice relaxation measurements; 2. The strong and weak collision regimes; D. Spin temperature; E. High resolution NMR of solids; 1. Magic angle spinning (MAS); 2. High power decoupling; 3. Cross polarization (CP) experiments; How to cool the protons |
| Summary |
This book is about pulse nuclear magnetic resonance (NMR), with its techniques, the information to be obtained, and practical advice on performing experiments. The emphasis is on the motivation and physical ideas underlying NMR experiments and the actual techniques, including the hardware used. The level is generally suitable for those to whom pulse NMR is a new technique, be they students in chemistry or physics on the one hand and research workers in biology, geology, or agriculture, on the other. The book can be used for a senior or first year graduate course where it could supplement the standard NMR texts |
| Bibliography |
Includes bibliographical references and indexes |
| Notes |
Online resource; title from PDF title page (EBSCO, viewed March 15, 2018) |
| Subject |
Nuclear magnetic resonance, Pulsed.
|
|
Nuclear magnetic resonance.
|
|
Magnetic Resonance Spectroscopy
|
|
nuclear magnetic resonance.
|
|
SCIENCE -- Physics -- Magnetism.
|
|
Nuclear magnetic resonance
|
|
Nuclear magnetic resonance, Pulsed
|
|
NMR-Spektroskopie
|
|
Pulsen.
|
|
Fourier-transformatie.
|
|
NMR.
|
| Form |
Electronic book
|
| Author |
Roeder, Stephen B. W.
|
| ISBN |
9780429493867 |
|
042949386X |
|
9780429973499 |
|
0429973497 |
|
