Description |
1 online resource (xii, 608 pages) : illustrations |
Series |
Grenoble sciences |
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Grenoble sciences
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Contents |
Introduction -- History of organometallic chemistry -- PART I STRUCTURES OF THE TRANSITION-METAL COMPLEXES Monometallic transition-metal complexes -- Bimetallic transition-metal complexes and clusters -- PART II THE STOICHIOMETRIC REACTIONS OF TRANSITION-METAL COMPLEXES Redox reactions, oxidative addition and s -- bond metathesis -- Reactions of nucleophiles and electrophiles with complexes -- Ligand substitution reactions -- Insertion and extrusion reactions -- PART III THE MAIN FAMILIES OF ORGANOMETALLIC COMPLEXES Metal carbonyls and complexes of other monohapto L ligands -- Metal-alkyl and -hydride complexes and other complexes of monohapto X ligands -- Metal-carbene and -carbyne complexes and multiple bonds with transition metals -- p complexes of mono- and polyenes and enyls -- Ionic and polar metal-carbon bonds: alkali and rare-earth complexes Metallocenes and sandwich complexes -- Covalent chemistry of the organoelements of frontier (11, 12) and main (13-16) groups -- PART IV CATALYSIS Hydrogenation and hydroelementation of alkenes -- Transformations of alkenes and alkynes -- Oxidation of olefins -- C-H activation and functionalization of alkanes and arenes -- Carbonylation and carboxylation reactions -- Bio-organometallic chemistry: enzymatic catalysis -- Heterogeneous catalysis -- PART V APPLICATIONS IN ORGANIC SYNTHESIS Organometallic complexes in organic synthesis Examples of applications -- Answers to exercises |
Summary |
This tutorial volume covers the basic and advanced aspects of organometallic chemistry of all metals and related catalysis topics. It treats historical background, concepts (including structures of mono- and polymetallic complexes), molecular orbitals, reactivity, implications in biology and applications to organic synthesis and catalysis. The catalysis section includes the challenging activation and functionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Chapter-end summaries and exercises support self- and group study, with solutions included at the end of the book. 500 selected references complement the text for further reading. Chapter-length treatment of green chemistry, plus many recent international research results, round out this highly accessible textbook. Organometallic Chemistry and Catalysis can profitably be read by beginners such as undergraduate and graduate students, as well as engineers, researchers and molecular scientists from academy and industry |
Analysis |
chemie |
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chemistry |
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organometaalverbindingen |
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organometallic compounds |
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katalyse |
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catalysis |
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anorganische scheikunde |
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inorganic chemistry |
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Chemistry (General) |
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Chemie (algemeen) |
Bibliography |
Includes bibliographical references (pages 553-589) and index |
Notes |
Translated from French |
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Print version record |
In |
Springer e-books |
Subject |
Organometallic chemistry.
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Organometallic chemistry -- Problems, exercises, etc
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Metal complexes.
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Organometallic chemistry.
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Metal complexes.
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Science des matériaux.
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Chimie.
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Metal complexes
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Organometallic chemistry
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Katalyse.
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Organometaalcomplexen.
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Genre/Form |
exercise books.
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Problems and exercises
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Problems and exercises.
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Problèmes et exercices.
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Form |
Electronic book
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ISBN |
9783540461296 |
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3540461299 |
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9783540461289 |
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3540461280 |
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