Limit search to available items
Book Cover
E-book
Author Astruc, D. (Didier)

Title Organometallic chemistry and catalysis / Didier Astruc
Published Berlin ; New York : Springer, ©2007

Copies

Description 1 online resource (xii, 608 pages) : illustrations
Series Grenoble sciences
Grenoble sciences
Contents Introduction -- History of organometallic chemistry -- PART I STRUCTURES OF THE TRANSITION-METAL COMPLEXES Monometallic transition-metal complexes -- Bimetallic transition-metal complexes and clusters -- PART II THE STOICHIOMETRIC REACTIONS OF TRANSITION-METAL COMPLEXES Redox reactions, oxidative addition and s -- bond metathesis -- Reactions of nucleophiles and electrophiles with complexes -- Ligand substitution reactions -- Insertion and extrusion reactions -- PART III THE MAIN FAMILIES OF ORGANOMETALLIC COMPLEXES Metal carbonyls and complexes of other monohapto L ligands -- Metal-alkyl and -hydride complexes and other complexes of monohapto X ligands -- Metal-carbene and -carbyne complexes and multiple bonds with transition metals -- p complexes of mono- and polyenes and enyls -- Ionic and polar metal-carbon bonds: alkali and rare-earth complexes Metallocenes and sandwich complexes -- Covalent chemistry of the organoelements of frontier (11, 12) and main (13-16) groups -- PART IV CATALYSIS Hydrogenation and hydroelementation of alkenes -- Transformations of alkenes and alkynes -- Oxidation of olefins -- C-H activation and functionalization of alkanes and arenes -- Carbonylation and carboxylation reactions -- Bio-organometallic chemistry: enzymatic catalysis -- Heterogeneous catalysis -- PART V APPLICATIONS IN ORGANIC SYNTHESIS Organometallic complexes in organic synthesis Examples of applications -- Answers to exercises
Summary This tutorial volume covers the basic and advanced aspects of organometallic chemistry of all metals and related catalysis topics. It treats historical background, concepts (including structures of mono- and polymetallic complexes), molecular orbitals, reactivity, implications in biology and applications to organic synthesis and catalysis. The catalysis section includes the challenging activation and functionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Chapter-end summaries and exercises support self- and group study, with solutions included at the end of the book. 500 selected references complement the text for further reading. Chapter-length treatment of green chemistry, plus many recent international research results, round out this highly accessible textbook. Organometallic Chemistry and Catalysis can profitably be read by beginners such as undergraduate and graduate students, as well as engineers, researchers and molecular scientists from academy and industry
Analysis chemie
chemistry
organometaalverbindingen
organometallic compounds
katalyse
catalysis
anorganische scheikunde
inorganic chemistry
Chemistry (General)
Chemie (algemeen)
Bibliography Includes bibliographical references (pages 553-589) and index
Notes Translated from French
Print version record
In Springer e-books
Subject Organometallic chemistry.
Organometallic chemistry -- Problems, exercises, etc
Metal complexes.
Organometallic chemistry.
Metal complexes.
Science des matériaux.
Chimie.
Metal complexes
Organometallic chemistry
Katalyse.
Organometaalcomplexen.
Genre/Form exercise books.
Problems and exercises
Problems and exercises.
Problèmes et exercices.
Form Electronic book
ISBN 9783540461296
3540461299
9783540461289
3540461280
Other Titles Chimie organométallique. English