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Book Cover
Author Volodarsky, L. B., author

Title Synthetic Chemistry of Stable Nitroxides / editors, V.A. Reznikov, V.I. Ovcharenko
Edition First edition
Published Boca Raton, FL : CRC Press, 2017
Online access available from:
ProQuest Ebook Central    View Resource Record  


Description 1 online resource : text file, PDF
Series CRC Press Revivals
Contents Cover; Title Page; Copyright Page; PREFACE; TABLE OF CONTENTS; Chapter 1. Introduction to Nitroxide Chemistry; I. The Subject of Nitroxide Chemistry; II. Stability of Nitroxide Radicals and the Scope of This Book; III. Brief Historical Review; IV. Classification and Nomenclature of Nitroxides; V. Purposes and Structure of This B ook; Acknowledgment; References; Chapter 2. Generation and Chemical Properties of the Nitroxyl Group; I. Methods of Generating the Nitroxyl Group; A. Oxidation of Hydroxylamines; B . Oxidation of Amines; C. Oxidative Transformations of Nitrones
2. Pyrrolines and Pyrrolidines3. Piperidines; D. Heterocyclic Nitroxides With an Additional Heteroatom in Heterocycle; 1. Five-Membered Heterocyclic Nitroxides; a. Oxazolidines; b. Imidazolidines; c. 2-Imidazolines and 2-Imidazoline- 3-Oxides; d. 3-Imidazoline-3-Oxides and 3-Imidazolines; 2. Six-Membered Heterocyclic Nitroxides; a. Tetrahydropyrimidines; b. Piperazines; c. Tetrahydrooxazines; 3. Seven-Membered Heterocyclic Nitroxides â#x80;#x94; Homopiperazines; E. Isotope-Substituted Stable Nitroxides; References; Chapter 4. Complexes With Metal-Nitroxyl Group Coordination; I. Introduction
D. Methods of Converting the Nitroso Group to the Nitroxyl GroupE. The Nitro Group as a Precursor of the Nitroxyl Group; F. Other Methods of Generating the Nitroxyl Group; II. Reactions of Nitroxides Involving the Nitroxyl Group; A. Reduction Reactions; B. Oxidation Reactions; C. Disproportionation Reactions; D. Reactions With Radicals; E. Photochemical Destruction of the Nitroxyl Group; References; Chapter 3. Synthetic Chemistry of Stable Nitroxides; I. Introduction; A. Molecular Biology, Biochemistry, and Biophysics; B. Coordination and Analytical Chemistry; C. Oxidation Catalysts
D. Stabilizers of Polymer and Monomer Materials, Antioxidants of Biochemical PreparatesE. Oil Field Geology; II. Synthetic Strategy for Functionalized Nitroxides; A. Direct Introduction of the Nitroxyl-Containing Fragment Into a Biogenic Molecule; B. Introduction of the Nitroxyl Group or Its Precursor With Simultaneous Frame Construction; III. Synthetic Chemistry of Stable Nitroxides; A. Protecting Groups in Synthesis of Functional Derivatives of Nitroxides; B. Acyclic Nitroxides; C. Cyclic Nitroxides Without an Additional Heteroatom in Heterocycle; 1. Three- and Four-Membered Nitroxides
II. Monofunctional NitroxideIII. Monofunctional Nitronyl Nitroxide; IV. Bifunctional Nitronyl Nitroxide With a Bridge Function; A. Specifics of the Approach; B. Limitations of the Approach; C. Derivatives of the 3-Imidazoline Nitroxide; D. Derivatives of the 2-Imidazoline Nitronyl Nitroxide; V. Trifunctional Nitroxide; A. Cu2+ Chelates Containing a Donor Group in an α-Position to the Nitroxyl Group; B. Metal Bischelates With a Bridging Coordination of the Nitroxide; 1. Copper β-Diketonates; 2. Metal Enamineketonates; VI. Molecular Ferromagnetics on the Basis of Complexes With Nitroxides
Summary "This important book is devoted to covering the synthetic aspects of nitroxide chemistry. The problems of application and physicochemical properties of nitroxides are considered in the context of the choice of necessary radical structures, convenient precursors, and strategy of the synthesis. The book offers comparisons of the concrete classes of nitroxides to help reveal the structural peculiarities and synthetic abilities of compounds of different classes. It also summarizes data on the magneto-structural correlation for the metal complexes with 3-imidazoline nitroxides and considers the ways in which the molecular design of 2- and 3-dimensional heterospin compounds is capable of magnetic phase transfer in a ferromagnetic state. The book will be a significant reference for chemists, biochemists, spectroscopists, and other users of nitroxides, spin labels, probes, and paramagnetic ligands."--Provided by publisher
Subject Nitroxides -- Synthesis
Form Electronic book
Author Ovcharenko, V. I., author.
Reznikov, V. A., author
ISBN 0203710150