| Description |
1 online resource (268 pages) |
| Contents |
Cover; Half Title; Title Page; Copyright Page; Contents; Preface; Author; Chapter 1: Effects of Ionic Strength; Some Preliminary Observations; Concepts and Equations; Additional Experimental Results; Conditional Constants and Thermodynamic Constants; Summary; References; Chapter 2: Monoprotic Acid-Base Equilibria: Exact and Approximate Options; Background Information; Exact Equation for the Hydrogen Ion Concentration; A Spreadsheet Program to Solve an Exact Equation for the Hydrogen Ion Concentration; Fractions and Concentrations of Conjugate Acid-Base Pairs |
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Program to Compare Hydrogen Ion Concentrations Calculated Using Exact and Approximate EquationsConventional Approximations; Unified Approximations; Graphical Comparisons of Approximation Errors; Summary; References; Chapter 3: Concepts and Equations Relevant to a Systematic Approach to Acid-Base Equilibria; A Theory of Acids and Bases and Some Related Terminology and Symbols; Roles of Hydrogen Ion Concentration and pH; Behaviors of Water, Strong Acids, Strong Bases, Weak Acids, and Weak Bases; Mass-Balance Equations; Concentration Fractions, Equilibrium Concentrations, and Distribution Plots |
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An Application of Concentration FractionsSummary; References; Chapter 4: A Systematic Approach to Monoprotic Acid-Base Equilibria without and with Correction for Ionic Strength; Systematic Approach to Monoprotic Acid-Base Equilibria; Spreadsheet Program for Calculations without Correction for Ionic Strength; Correction for Ionic Strength; Selected Applications of the Spreadsheet Program, Monoprotic_Systematic; Distribution Plots; Program to Calculate and Plot pH vs. Titrant Volume; Summary; References |
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Chapter 5: A Systematic Approach to Monoprotic, Diprotic, and Polyprotic Acid-Base EquilibriaPreview of Equations for the Hydrogen Ion Concentration and Ionic Strength and a Program to Solve Them; Overview of the Program on Sheet 1 of the Acid-Base Program; Some Examples; Mixtures of Up to Three Weak Acids and Their Conjugate Bases; Solving the Charge-Balance Equation for the Hydrogen Ion Concentration; Basis for Charge-Balance Equations; Correction for Ionic Strength; Activity Coefficients; Relationships among Activity-Based and Concentration-Based Constants; Summary; References |
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Chapter 6: Some Applications of Acid-Base EquilibriaTitration Curves; Overview of Acid-Base Buffers; Measures of Buffer Performance; Summary; References; Chapter 7: Solubility Equilibria; Some Background Information; Salts of Strong Acids; Sparingly Soluble Hydroxides; Sparingly Soluble Salts of Weak Acids without Common Ions; Sparingly Soluble Salts of Weak Acids with Common Ions; Summary; References; Chapter 8: Overview and Symbols for Complex Ion Reactions and Equilibria; Reactants and Reactions; The Chelate Effect; Charges on Reactants and Products; Multistep and One-Step Reactions |
| Notes |
Some Goals and Resulting Symbols |
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Print version record |
| Subject |
Chemical equilibrium.
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Chemical equilibrium -- Mathematics
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Acid-base equilibrium.
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Neutralization (Chemistry)
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neutralization.
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Acid-base equilibrium.
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Chemical equilibrium.
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Chemical equilibrium -- Mathematics.
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Neutralization (Chemistry)
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| Form |
Electronic book
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| ISBN |
9780429771347 |
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0429771347 |
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