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Book Cover
Author Pardue, Harry L

Title Chemical Equilibria : Exact Equations and Spreadsheet Programs to Solve Them
Published Milton : Chapman and Hall/CRC, 2018


Description 1 online resource (268 pages)
Contents Cover; Half Title; Title Page; Copyright Page; Contents; Preface; Author; Chapter 1: Effects of Ionic Strength; Some Preliminary Observations; Concepts and Equations; Additional Experimental Results; Conditional Constants and Thermodynamic Constants; Summary; References; Chapter 2: Monoprotic Acid-Base Equilibria: Exact and Approximate Options; Background Information; Exact Equation for the Hydrogen Ion Concentration; A Spreadsheet Program to Solve an Exact Equation for the Hydrogen Ion Concentration; Fractions and Concentrations of Conjugate Acid-Base Pairs
Program to Compare Hydrogen Ion Concentrations Calculated Using Exact and Approximate EquationsConventional Approximations; Unified Approximations; Graphical Comparisons of Approximation Errors; Summary; References; Chapter 3: Concepts and Equations Relevant to a Systematic Approach to Acid-Base Equilibria; A Theory of Acids and Bases and Some Related Terminology and Symbols; Roles of Hydrogen Ion Concentration and pH; Behaviors of Water, Strong Acids, Strong Bases, Weak Acids, and Weak Bases; Mass-Balance Equations; Concentration Fractions, Equilibrium Concentrations, and Distribution Plots
An Application of Concentration FractionsSummary; References; Chapter 4: A Systematic Approach to Monoprotic Acid-Base Equilibria without and with Correction for Ionic Strength; Systematic Approach to Monoprotic Acid-Base Equilibria; Spreadsheet Program for Calculations without Correction for Ionic Strength; Correction for Ionic Strength; Selected Applications of the Spreadsheet Program, Monoprotic_Systematic; Distribution Plots; Program to Calculate and Plot pH vs. Titrant Volume; Summary; References
Chapter 5: A Systematic Approach to Monoprotic, Diprotic, and Polyprotic Acid-Base EquilibriaPreview of Equations for the Hydrogen Ion Concentration and Ionic Strength and a Program to Solve Them; Overview of the Program on Sheet 1 of the Acid-Base Program; Some Examples; Mixtures of Up to Three Weak Acids and Their Conjugate Bases; Solving the Charge-Balance Equation for the Hydrogen Ion Concentration; Basis for Charge-Balance Equations; Correction for Ionic Strength; Activity Coefficients; Relationships among Activity-Based and Concentration-Based Constants; Summary; References
Chapter 6: Some Applications of Acid-Base EquilibriaTitration Curves; Overview of Acid-Base Buffers; Measures of Buffer Performance; Summary; References; Chapter 7: Solubility Equilibria; Some Background Information; Salts of Strong Acids; Sparingly Soluble Hydroxides; Sparingly Soluble Salts of Weak Acids without Common Ions; Sparingly Soluble Salts of Weak Acids with Common Ions; Summary; References; Chapter 8: Overview and Symbols for Complex Ion Reactions and Equilibria; Reactants and Reactions; The Chelate Effect; Charges on Reactants and Products; Multistep and One-Step Reactions
Notes Some Goals and Resulting Symbols
Print version record
Subject Chemical equilibrium.
Chemical equilibrium -- Mathematics
Acid-base equilibrium.
Neutralization (Chemistry)
Acid-base equilibrium.
Chemical equilibrium.
Chemical equilibrium -- Mathematics.
Neutralization (Chemistry)
Form Electronic book
ISBN 9780429771347