| Description |
1 online resource |
| Series |
Advanced chemistry texts ; v. 5 |
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Advanced chemistry texts ; v. 5.
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| Contents |
Cover; Half Title; Title Page; Copyright Page; Dedication; Table of Contents; Preface; Chapter 1 Introduction; 1.1 History; 1.1.1 Lanthanides; 1.1.2 Actinides; 1.2 Sources of the Elements; 1.2.1 Lanthanum, yttrium and the lanthanides; 1.2.2 Actinides; 1.3 Applications of Rare Earths and Actinides; 1.3.1 Lanthanum, yttrium and the lanthanides; 1.3.2 Actinides; Thorium; Uranium; Plutonium; Americium; 1.4 Properties of the Elements; 1.4.1 The metals; 1.4.2 Shapes of f-orbitals; 1.4.3 The lanthanide and actinide contractions; 1.4.4 Electronic Configurations; Lanthanides; Actinides |
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1.4 .5 Magnetic properties1.4.6 Oxidation States; Lanthanides; Actinides; 1.5 Binary Compounds; 1 .5. 1 Oxides o f the lanthanides; 1.5.2 Halides of the lanthanides; Fluorides; Chlorides; Bromides and Iodides; 1.5.3 Oxides of the actinides; 1.5.4 Halides of the actinides; Fluorides; UF6 in uranium isotope separation; Chlorides; Bromides and Iodides; Chapter 2 Spectroscopy; 2.1 Electronic Absorption Spectroscopy; 2.2 Lanthanide Luminescence; Sensitized luminescence; 2.2 . 1 luminescence Spectroscopy; 2.2 . 2 Applications of lanthanide luminescence in lighting and displays |
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2.2.3 Neodymium lasers2.3 Nuclear Magnetic Resonance; 2.3.1 NMR spectroscopy of paramagnetic complexes; 2.3.2 Lanthanide shift reagents; Chiral lanthanide shift reagents; Lanthanide shift reagents for use in biological systems; 2.3.3 Gd3+ Complexes in Magnetic Resonance Imaging; 2.3.4 NMR Spectroscopy of lanthanide nuclei; 2.4 EPR Spectroscopy; Chapter 3 Coordination Chemistry; 3.1 Coordination Chemistry of Lanthanide and Actinide Ions in Aqueous Solution; 3.1.1 Lanthanides; 3.1.2 Acti nides; Oxidation state +2; Oxidation state +3; Oxida tion state +4; Oxidation state +5; Oxidation state +6 |
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Oxidation state +73.1.3 Complex formation in aqueous solution; Simple anions; Multidentate ligands; Aminopolycarboxylates; 3.2 Complexes with Neutral O-Donor Ligands; 3.2.1 Phosphine, arsine and amine oxides; 3.2.2 Acyclic and cyclic polyethers -- podands, crowns and cryptands; 3.3 Complexes with Anionic O-Donors; 3.3.1 Alkoxide and Aryloxide Complexes; Lanthanide(III) complexes; Ln allcoxides in other oxidation states; Reactivity; Applications; Actinides; Synthesis; 3.3.2 ß-Diketonate Complexes; Lanthanides; Actinides; Synthesis; 3.4 Complexes with Neutral N-Donor Ligands |
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3.4.1 Aromatic N-donors3.4. 2 Schiff base macrocycles; 3.5 Complexes with Anionic N-Donors; 3.5.1 Hexamethyldisilylamide Complexes; Lanthanides; Actinides; 3.5.2 Dialkylamide Complexes; Lanthanides; Actinides; 3.6 Complexes with Heavier Donor Atoms; 3.6.1 Complexes with P-donor Ligands; Complexes with Neutral P-donors; Lanthanides; Actinides; Complexes with Phosphido ligands; Lanthanides; Actinides; 3.6.2 Complexes with S-donor ligands; Neutral S-donors; Thiolates; Dithiocarbamates, dithiophosphinates and dithiophosphates |
| Bibliography |
Includes bibliographical references and index |
| Subject |
Rare earth metals.
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Actinide elements.
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SCIENCE -- Chemistry -- Inorganic.
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Actinide elements.
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Rare earth metals.
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| Form |
Electronic book
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| ISBN |
9781315139258 |
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1315139251 |
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