| Description |
1 online resource (xxv, 1234 pages) : illustrations (some color) |
| Contents |
880-01 Cover; Contents; Abbreviations; Preface to the second edition; Organic chemistry and this book; 1 What is organic chemistry?; Organic chemistry and you; Organic compounds; Organic chemistry and industry; Organic chemistry and the periodic table; Organic chemistry and this book; Further reading; 2 Organic structures; Hydrocarbon frameworks and functional groups; Drawing molecules; Hydrocarbon frameworks; Functional groups; Carbon atoms carrying functional groups can be classified by oxidation level; Naming compounds; What do chemists really call compounds?; How should you name compounds? |
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880-01/(S The conjugation of two π bondsUV and visible spectra; The allyl system; Delocalization over three atoms is a common structural feature; Aromaticity; Further reading; 8 Acidity, basicity, and pK[sub(a)]; Organic compounds are more soluble in water as ions; Acids, bases, and pK[sub(a)]; Acidity; The definition of pK[sub(a)]; Constructing a pK[sub(a)] scale; Nitrogen compounds as acids and bases; Substituents affect the pK[sub(a)]; Carbon acids; pK[sub(a)] in action-the development of the drug cimetidine; Lewis acids and bases; Further reading; 9 Using organometallic reagents to make C-C bonds |
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Further reading3 Determining organic structures; Introduction; Mass spectrometry; Mass spectrometry detects isotopes; Atomic composition can be determined by high-resolution mass spectrometry; Nuclear magnetic resonance; Regions of the [sup(13)]C NMR spectrum; Different ways of describing chemical shift; A guided tour of the [sup(13)]C NMR spectra of some simple molecules; The [sup(1)]H NMR spectrum; Infrared spectra; Mass spectra, NMR, and IR combined make quick identification possible; Double bond equivalents help in the search for a structure; Looking forward to Chapters 13 and 18 |
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Further reading4 Structure of molecules; Introduction; Electrons occupy atomic orbitals; Molecular orbitals-diatomic molecules; Bonds between different atoms; Hybridization of atomic orbitals; Rotation and rigidity; Conclusion; Looking forward; Further reading; 5 Organic reactions; Chemical reactions; Nucleophiles and electrophiles; Curly arrows represent reaction mechanisms; Drawing your own mechanisms with curly arrows; Further reading; 6 Nucleophilic addition to the carbonyl group; Molecular orbitals explain the reactivity of the carbonyl group; Attack of cyanide on aldehydes and ketones |
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The angle of nucleophilic attack on aldehydes and ketonesNucleophilic attack by 'hydride' on aldehydes and ketones; Addition of organometallic reagents to aldehydes and ketones; Addition of water to aldehydes and ketones; Hemiacetals from reaction of alcohols with aldehydes and ketones; Ketones also form hemiacetals; Acid and base catalysis of hemiacetal and hydrate formation; Bisulfite addition compounds; Further reading; 7 Delocalization and conjugation; Introduction; The structure of ethene (ethylene, CH[sub(2)]=CH[sub(2)]); Molecules with more than one C=C double bond |
| Summary |
A first- and second-year undergraduate organic chemistry textbook, specifically geared to British and European courses and those offered in better schools in North America, this text emphasises throughout clarity and understanding |
| Notes |
Revised edition of: Organic chemistry / Jonathan Clayden [and others] |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002. http://purl.oclc.org/DLF/benchrepro0212 MiAaHDL |
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Print version record |
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digitized 2021. HathiTrust Digital Library committed to preserve pda MiAaHDL |
| Subject |
Chemistry, Organic -- Textbooks
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SCIENCE -- Chemistry -- Organic.
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Science.
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Chemistry, Organic
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Organische Chemie
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| Genre/Form |
Textbooks
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| Form |
Electronic book
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| Author |
Greeves, Nick
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Warren, Stuart G
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| LC no. |
2011943531 |
| ISBN |
9780191666216 |
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0191666211 |
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9780192518545 |
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0192518542 |
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