| Description |
1 online resource (441 pages) |
| Contents |
Cover; Half Title; Title Page; Copyright Page; Dedication; Table of Contents; Preface; Author; Chapter 1: Clays and Clay Minerals: Structures, Compositions, and Properties; 1.1 Concepts and Definitions; 1.2 Structural Aspects; 1.3 Specific Structural and Surface Properties; 1.3.1 Kaolinite; 1.3.2 Halloysite; 1.3.3 Chrysotile; 1.3.4 Smectite; 1.3.5 Vermiculite; 1.3.6 Chlorite; 1.3.7 Mica, Illite, Synthetic Mica-Montmorillonite, and Fluorotetrasilicic Mica; 1.3.8 Sepiolite and Palygorskite; 1.3.9 Allophane and Imogolite; References; Chapter 2: Surface Acidity and Catalytic Activity |
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2.1 Introduction2.2 Acids and Bases; 2.2.1 Acid Strength; 2.3 Brønsted Acidity; 2.4 Lewis Acidity; 2.5 Brønsted-Lewis Acid Combination and Synergy; 2.6 Concentration and Distribution of Surface Acid Sites; 2.6.1 Amine Titration; 2.6.2 Adsorption and Desorption of Basic Probe Molecules; References; Chapter 3: Surface Activation and Modification; 3.1 Introduction; 3.2 Acid Activation; 3.3 Thermal Activation and Related Treatments; 3.3.1 Heating and Calcination; 3.3.2 Microwave and Ultrasound Irradiation; 3.4 Pillared Interlayered Clays and Porous Clay Heterostructures |
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3.5 Organically Modified Clay Minerals3.5.1 Organoclays and Related Materials; 3.5.2 Surface Grafting and Silylation; References; Chapter 4: Organic Catalysis by Clay-Supported Reagents; 4.1 Introduction; 4.2 Clay-Supported Metal Salts; 4.2.1 Clay-Supported Zinc(II) Chloride and Other Metal Chlorides; 4.2.2 Clay-Supported Iron(III) Nitrate and Other Metal Nitrates; 4.3 Clay-Supported Metal Oxides and Metal Sulfides; 4.4 Clay-Supported Metal Nanoparticles; 4.5 Clay-Supported Organic and Metal-Organic Reagents; 4.6 Clay-Supported Heteropolyacids; References |
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Chapter 5: Clay Mineral Catalysis of Name Reactions5.1 Introduction; 5.2 Alder-Ene Reaction; 5.3 Baeyer-Villiger Condensation and Oxidation; 5.4 Bamberger Rearrangement; 5.5 Baylis-Hillman Reaction; 5.6 Beckmann Rearrangement; 5.7 Biginelli Reaction; 5.8 Diels-Alder Reaction; 5.9 Ferrier Rearrangement; 5.10 Fischer Glycosidation/Glycosylation; 5.11 Fischer-Hepp Rearrangement; 5.12 Fischer Indole Synthesis; 5.13 Fischer-Tropsch Synthesis; 5.14 Friedel-Crafts Reaction; 5.15 Friedländer Synthesis; 5.16 Fries Rearrangement; 5.17 Hantzsch Dihydropyridine Synthesis; 5.18 Heck Reaction |
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5.19 Knoevenagel Condensation5.20 Mannich Reaction; 5.21 Markovnikov Addition Rule; 5.22 Michael Addition; 5.23 Mukaiyama Aldol Reaction; 5.24 Nicholas Reaction; 5.25 Oppenauer Oxidation; 5.26 Paal-Knorr Synthesis; 5.27 Pechmann Condensation; 5.28 Prins Reaction; 5.29 Ritter Reaction; 5.30 Sakurai Allylation Reaction; 5.31 Sonogashira Reaction; 5.32 Strecker Reaction; 5.33 Suzuki Reaction; 5.34 Wacker Oxidation; 5.35 Wittig Reaction; References; Chapter 6: Clay Mineral Catalysis of Isomerization, Dimerization, Oligomerization, and Polymerization Reactions; 6.1 Introduction; 6.2 Isomerization |
| Notes |
6.2.1 Hydrocarbons |
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Print version record |
| Form |
Electronic book
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| ISBN |
9780429879678 |
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0429879679 |
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