| Description |
1 online resource (403 p.) |
| Contents |
Cover -- Half Title -- Title -- Copyright -- Brief Contents -- Detailed Contents -- Preface -- Part-I: Coordination Chemistry -- 1. History of Complexes -- 1.1 Complexes -- 1.1.1 History -- 1.2 Difference Between Double Salts and Complex Compounds -- 1.2.1 Addition Compounds -- 2. Introduction -- Coordination or Complex Compounds -- 2.1 Coordination Sphere -- Ligands -- 2.2 Formation of a Complex -- Coordination Number (C.N.) -- Low Coordination Numbers -- Four Coordination Complexes -- Five Coordinate Geometry -- Six Coordinate Complexes -- Distortion -- High Coordination Complexes |
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Eight Coordinate Complexes -- 2.3 Bridging Ligands -- 2.3.1 Non-Chelates -- 2.3.2 Chelates -- 3. Correct Empirical Formula of Complexes -- 3.1 Precipitation Method -- 3.2 Molar Conductivity Method -- 3.3 Effective Atomic Number (EAN Rule) -- 3.4 Blomstrand-Jorgensen Chain Theory -- 3.5 Werner's Coordination Theory -- 4. IUPAC System of Nomenclature -- 4.1 Nomenclature of Coordination Compounds -- 4.2 General Rules -- 4.3 Naming the Metal Ion -- 4.4 Naming the Ligand -- Configuration Symbols -- Naming the Inner Complexes -- 5. Isomerism and Stereochemistry -- 5.1 Isomerism |
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5.2 Structural Isomerism -- Coordination Position Isomerism -- Ionisation Isomerism -- Compound -- Hydrate Isomerism -- Linkage Isomerism -- Ligand Isomerism -- Polymerisation Isomerism -- Other Uncommon Isomerism -- Spin Isomerism -- Summation Isomerism -- Valence Isomerism -- Distortional Isomerism -- 5.3 Stereoisomerism -- 6. Bonding in Complexes -- 6.1 Nature of Metal-Ligand Bond -- 6.2 Lewis Acid-Base Theory -- 6.3 Valence Bond Theory -- 6-Coordinate Octahedral Complexes -- Outer Orbital Complexes -- Inner Orbital Complexes -- Limitations of VBT (Valency Bond Theory) |
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8.2 Factors Influencing Stability -- 9. Kinetics or Inert and Labile Complexes -- 9.1 Introduction -- Effective Collision -- 9.2 Inert and Labile Complexes -- 9.2.1 Classifi cation of Inert and Labile Complexes on the Basis of Electrons in d Orbitals -- 9.2.2 Inert and Labile Complexes on the Basis of CFSE -- 9.2.3 Roie of a Cataiysi (Kinetics) -- 10. Substitution Reactions in Complexes -- 10.1 Introduction -- 10.2 Mechanism of Substitution -- 10.3 Substitution in Non-Aqueous Solvents -- 10.4 Substitution When No Solvent Is Used -- 10.5 Mechanisms of Substitution -- Select Topics |
| Notes |
Description based upon print version of record |
|
11. Coordination Complexes and Biological Systems |
| Form |
Electronic book
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| Author |
Soni, Vandna
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| ISBN |
9781000404135 |
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1000404137 |
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