| Description |
1 online resource (434 p.) |
| Contents |
Cover -- Title Page -- Copyright -- Contents -- Foreword -- Preface -- Chapter 1 Role of Biomass in the Production of Chemicals -- 1.1 Introduction -- 1.2 Biomass Valorization -- 1.3 Lignocellulosic Biomass -- 1.4 Key Biomolecules -- 1.5 Solvents -- 1.6 Pretreatment of Lignocelluloses -- 1.7 Conclusions and Perspectives -- References -- Section I Catalytic Strategies -- Chapter 2 Biomass Processing via Acid Catalysis -- 2.1 Introduction -- 2.1.1 Is an Acid the Best Catalyst? -- 2.2 Acid-Catalyzed Processing of Cellulosic Polysaccharides -- 2.3 Acid-Catalyzed Processing of Lignin |
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2.4 Conclusions and Perspectives -- References -- Chapter 3 Biomass Processing via Base Catalysis -- 3.1 Introduction -- 3.2 Aldol Condensation -- 3.2.1 Aldol Condensation of Furanic Aldehydes -- 3.2.2 Self-Aldol Condensation of Acetone -- 3.2.3 Aldol Condensation Between Alcohols: Guerbet Coupling Reaction -- 3.3 Ketonization Reaction of Carboxylic Acids -- 3.4 Transesterification Reaction -- 3.4.1 Biodiesel Production -- 3.4.2 High Value-Added Chemicals from Transesterification Reactions -- 3.5 Conclusions and Perspectives -- References -- Chapter 4 Biomass Processing via Metal Catalysis |
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4.1 Introduction -- 4.2 Synthetic Strategies for Supported Metal Nanoparticles -- 4.2.1 Impregnation -- 4.2.2 Precipitation -- 4.2.3 Sol Immobilization -- 4.3 Furfural -- 4.3.1 Furfural Hydrogenation -- 4.3.1.1 Furfural to Furfuryl Alcohol -- 4.3.1.2 Furfural to Tetrahydrofurfuryl Alcohol -- 4.3.1.3 Furfural to Pentanediols -- 4.3.1.4 Furfural to 2-Methylfuran -- 4.3.2 Furfural Oxidation -- 4.3.2.1 Furfural to Furoates -- 4.4 5-Hydroxymethylfurfural (HMF) -- 4.4.1 HMF Hydrogenation -- 4.4.1.1 HMF to 2,5-Dimethylfuran (DMF) -- 4.4.1.2 HMF to 2,5-Dihydroxymethyltetrahydrofuran (DHMTHF) |
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4.4.2 HMF Oxidation -- 4.4.2.1 HMF to 2,5-Furandicarboxylic Acid (FDCA) Using Monometallic Systems -- 4.4.2.2 HMF Oxidation over Bimetallic Catalysts -- 4.5 Conclusions and Perspectives -- References -- Chapter 5 Biomass Processing with Biocatalysis -- 5.1 Introduction -- 5.2 Generations of Renewable Biomass: Advantages and Limitations -- 5.3 Advantages and Limitations of Biocatalysis -- 5.4 Enzyme Discovery and Optimization of Enzyme Performance -- 5.5 Enzyme Immobilization -- 5.5.1 Enzyme Immobilization by Cross-linking Enzyme Molecules |
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5.5.2 Advantages and Limitations of Cross-Linked Enzyme Aggregates (CLEAs) -- 5.5.3 Magnetically Separable Immobilized Enzymes -- 5.6 Enzymatic Hydrolysis of Starch to Glucose -- 5.7 Enzymatic Depolymerization of Lignocellulose -- 5.8 Enzymatic Hydrolysis of Cellulose and Hemicellulose -- 5.8.1 Magnetizable Immobilized Enzymes in Lignocellulose Conversion -- 5.9 Enzymatic Hydrolysis of 3rd Generation (3G) Polysaccharides -- 5.10 Commodity Chemicals from Carbohydrates (Monosaccharides) -- 5.10.1 Fermentative Production of Commodity Chemicals |
| Notes |
Description based upon print version of record |
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5.10.2 Deoxygenation via Dehydration of Carbohydrates to Furan Derivatives |
| Form |
Electronic book
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| Author |
Samori, Chiara
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| ISBN |
9783527825011 |
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3527825010 |
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