Title Pillararenes / editor: Tomoki Ogoshi

Published [Cambridge] : Royal Society of Chemistry, [2015] ©2016

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Description 1 online resource Series Monographs in supramolecular chemistry ; 18 Monographs in supramolecular chemistry ; 18. Contents Cover; Contents; Preface; Chapter 1 Historical Background of Macrocyclic Compounds; 1.1 Introduction; 1.2 Cyclodextrins; 1.3 Crown Ethers and Their Derivatives; 1.4 Calix[n]arenes and Their Derivatives; 1.5 Cucurbit[n]urils CB[n] and Their Derivatives; 1.6 Other Synthetic Macrocyclic Compounds; 1.7 Conclusion and Outlook; References; Chapter 2 Synthesis of Pillar[n]arenes; 2.1 Introduction; 2.2 Synthesis of Pillar[5] arenes; 2.2.1 Synthesis of Pillar[5]arene from 1,4-Dimethoxybenzene as a Monomer; 2.2.2 Synthesis of Pillar[5]arenes from 1,4-Dialkoxybenzene Monomers 2.2.3 Mechanism of the Formation of Pillar[5]arenes -- Thermodynamic Control2.3 Synthesis of Pillar[6]arenes under Kinetic and Thermodynamic Control; 2.4 Synthesis of Larger Pillar[n]arene Homologs under Kinetic Control; 2.5 Conclusion and Outlook; References; Chapter 3 Functionalization of Pillararenes; 3.1 Introduction; 3.2 Per-functionalization of Pillar[n]arenes by Pre-formed Pillar[n]arenes; 3.3 Per-functionalization of Pillar[n]arenes by Cyclization of Dialkoxybenzene Derivatives with Reactive Moieties; 3.4 Mono-functionalization of Pillar[5]- and Pillar[6]arenes 3.5 Di-functionalized Pillar[5]- and Pillar[6]arenes3.6 Functionalized Pillar[5] arenes with More Than Three Diifferent Substituents; 3.7 Conclusion and Outlook; References; Chapter 4 Conformation and Planar Chirality of Pillar[n]arenes; 4.1 Introduction; 4.2 Conformation of Pillar[5]arenes; 4.2.1 Conformation of Pillar[5]arenes with Simple Alkyl Substituents; 4.2.2 Conformation of Pillar[5]arenes with One p-Conjugated Unit; 4.2.3 Conformation of Hydroxylated Pillar[5]arenes; 4.2.4 Conformation of Non-symmetrical Pillar[5]arenes; 4.3 Conformations of Pillar[6]arenes 4.3.1 Conformation of Symmetrical Per-alkylated Pillar[6]arenes4.3.2 Conformation of Per-hydroxylated Pillar[6]arene; 4.4 Conclusion and Outlook; References; Chapter 5 Host-Guest Properties of Pillar[n]arenes; 5.1 Introduction; 5.2 X-ray Crystal Structure and Electron Potential Profiles of Pillar[n]arenes; 5.3 Host-Guest Properties of Pillar[5]arenes; 5.3.1 per-Hydroxylated Pillar[5]arene; 5.3.2 per-Alkylated Pillar[5]arenes; 5.3.3 Water-soluble Pillar[5]arenes; 5.3.4 Functionalized Pillar[5]arenes; 5.4 Host-Guest Properties of Pillar[6]arenes; 5.4.1 per-Hydroxylated Pillar[6]arene 5.4.2 per-Alkylated Pillar[6]arenes5.4.3 Water-soluble Pillar[6]arenes; 5.4.4 Functionalized Pillar[6]arenes; 5.5 Host-Guest Properties of LargerPillar[n]arene Homologs (n = 7-14); 5.6 Summary and Outlook; References; Chapter 6 Assembled Structures of Pillar[n]arenes; 6.1 Introduction; 6.2 Assembled Structures of Pillar[5]arenes in Crystal States; 6.2.1 per-Alkylated Pillar[5]arenes; 6.2.2 per-Functionalized Pillar[5]arenes; 6.2.3 A1/A2 Pillar[5]arenes; 6.2.4 Pillar[5]arenes with Two and Three Benzoquinone Units; 6.2.5 Non-symmetrical Pillar[5]arenes Summary First reported in 2008, Pillararenes are a new class of macrocyclic hosts consisting of hydroquinone units linked at the para-position. With a composition similar to cucurbiturils and calixarenes, they combine the advantages and aspects of traditional hosts and have applications in sensing, material synthesis and biomedicine. Pillararenes starts with the historical background of macrocyclic compounds and then following chapters cover the synthesis of pillararenes, their structures, conformations and planar chirality. Dedicated chapters then cover their host-guest properties and supramolecular assemblies based on pillararenes including supramolecular polymers and mechanically interlocked molecules. Edited by the leader in the field, this is the first book to cover pillararenes and will appeal to graduate students, researchers and academics in supramolecular chemistry, organic chemistry, polymer chemistry and materials science interested in the chemistry and applications of pillararenes Notes Includes index English Online resource; title from title details screen (Royal Society of Chemistry, viewed November 19, 2015) Subject Macrocyclic compounds. Supramolecular chemistry. Molecular structure. Chemistry. Nitrogen compounds. Chemotherapy. Polycyclic compounds. Physical sciences. Amines. Phenols. Manufactures. Therapeutics. Organic compounds. Inorganic compounds. Quaternary Ammonium Compounds Drug Delivery Systems Macrocyclic Compounds Hydroquinones Molecular Structure Nanostructures Chemistry Chemical Phenomena Nitrogen Compounds Drug Therapy Biochemical Phenomena Polycyclic Compounds Onium Compounds Natural Science Disciplines Amines Phenols Manufactured Materials Therapeutics Phenomena and Processes Organic Chemicals Inorganic Chemicals Chemicals and Drugs Disciplines and Occupations Technology, Industry, and Agriculture Technology, Industry, Agriculture Analytical, Diagnostic and Therapeutic Techniques and Equipment molecular structure. chemistry. nitrogen compounds. physical sciences. organic compounds. treating (health care function) SCIENCE -- Chemistry -- Organic. Therapeutics Polycyclic compounds Physical sciences Phenols Organic compounds Nitrogen compounds Molecular structure Manufactures Inorganic compounds Chemotherapy Chemistry Amines Macrocyclic compounds Supramolecular chemistry Form Electronic book Author Ogoshi, Tomoki, editor Royal Society of Chemistry (Great Britain) ISBN 9781782622321 1782622322

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