| Description |
1 online resource |
| Series |
Developments in clay science ; v. 9 |
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Developments in clay science ; 9.
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| Contents |
Front Cover; Surface and Interface Chemistry of Clay Minerals; Copyright; Dedication; Contents; Contributors; Preface; Acknowledgements; Chapter 1: Clay minerals and their surfaces; 1.1. TO or 1:1 and TOT or 2:1 clay minerals; 1.2. Structural considerations; 1.3. Isomorphous substitution; 1.4. Consequences of isomorphous substitution; 1.4.1. Cation exchange; 1.4.2. Cation exchange capacity; 1.4.3. Intercalation and swelling; 1.5. Surfaces, surface areas, and surface sites; 1.6. Surface atoms; 1.7. Molecule-molecule and molecule-surface interactions; 1.7.1. Molecule-molecule interactions |
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1.7.1.1. Ion-ion interactions1.7.1.2. Dipole-dipole interactions; 1.7.1.3. Charge-nonpolar interaction; 1.7.1.4. Dipolar-nonpolar interaction; 1.7.1.5. Nonpolar-nonpolar interactions; 1.7.1.6. H-bonding: X-H -- Y; 1.7.2. Molecule-surface and surface-surface interactions; References; Further reading; Chapter 2: Determination of surface areas and textural properties of clay minerals; 2.1. Introduction; 2.2. Nonswelling and nonmicroporous clay minerals; 2.3. Microporous clay minerals; 2.4. Swelling clay minerals; 2.4.1. The dry state |
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2.4.1.1. Gas adsorption techniques using ̀classical adsorbates2.4.1.2. Adsorption techniques using polar adsorbates; 2.4.2. Swelling clay minerals dispersions; 2.5. Concluding remarks; References; Chapter 3: Quantum-chemical modelling of clay mineral surfaces and clay mineral-surface-adsorbate interactions; 3.1. Quantum mechanical description of interatomic interactions; 3.1.1. Hartree-Fock method; 3.1.2. Density functional theory; 3.1.3. Dispersion correction; 3.1.4. Basis set; 3.1.5. Effective core potentials; 3.1.6. System size and boundary conditions |
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3.1.7. Structural optimisation and molecular dynamics simulations3.1.8. Ab initio spectroscopy; 3.2. Simulations of clay minerals structure; 3.2.1. Structure of TO/TOT layer and isomorphous substitutions; 3.2.2. Structure of hydroxyl layer in 1:1 clay minerals; 3.2.3. Structure of the interlayer and basal plane in 2:1 clay minerals; 3.3. Elastic properties of clay minerals; 3.4. Redox processes; 3.5. Interaction of clay minerals with organic compounds; 3.5.1. Natural organic matter and environmental engineering; 3.5.2. Organic contaminants; 3.5.3. Pillared organo-clay nanocomposites |
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3.5.4. Interaction with petroleum molecules3.5.5. Adsorption of biomolecules; 3.6. Acid-base properties of edge surfaces and cation complexation; 3.6.1. Edge surface structures and surface pKa; 3.6.2. Metal complexation at edge sites; 3.7. Outlook; References; Chapter 4: Clay mineral-water interactions; 4.1. Introduction; 4.2. Water interactions with ̀neutral clay mineral surfaces; 4.2.1. Talc and pyrophyllite; 4.2.2. Kaolin group mineral; 4.2.2.1.1. Kaolinite; 4.2.2.1.2. Halloysite; 4.3. Water interactions with ̀charged clay mineral surfaces (ion-dipole); 4.3.1. Smectites |
| Summary |
Surface and Interface Chemistry of Clay Minerals, Volume 9, delivers a fundamental understanding of the surface and interface chemistry of clay minerals, thus serving as a valuable resource for researchers active in the fields of materials chemistry and sustainable chemistry. Clay minerals, with surfaces ranging from hydrophilic, to hydrophobic, are widely studied and used as adsorbents. Adsorption can occur at the edges and surfaces of clay mineral layers and particles, and in the interlayer region. This diversity in properties and the possibility to tune the surface properties of clay minerals to match the properties of adsorbed molecules is the basis for study. This book requires a fundamental understanding of the surface and interface chemistry of clay minerals, and of the interaction between adsorbate and adsorbent. It is an essential resource for clay scientists, geologists, chemists, physicists, material scientists, researchers, and students |
| Notes |
Vendor-supplied metadata |
| Subject |
Clay.
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Interfaces (Physical sciences)
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clay.
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TECHNOLOGY & ENGINEERING -- Engineering (General)
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TECHNOLOGY & ENGINEERING -- Reference.
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Clay
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Interfaces (Physical sciences)
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| Form |
Electronic book
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| Author |
Schoonheydt, Robert, editor
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Johnston, C. T., editor
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Bergaya, Faïza, editor.
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| ISBN |
9780081024331 |
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0081024339 |
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