| Description |
1 online resource |
| Series |
Fuel cells and hydrogen energy |
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Fuel cells and hydrogen energy.
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| Contents |
Cover -- Contents -- 1 Structure and Properties of Perovskite Oxides -- 1.1 Introduction -- 1.2 Structure of Perovskite Oxides -- 1.3 Typical Properties of Perovskite Oxides -- 1.4 Preparation of Perovskite Oxide -- 1.5 Perovskite Oxides for Solid Oxide Fuel Cells (SOFCs) -- References -- 2 Overview of Intermediate-Temperature Solid Oxide Fuel Cells -- 2.1 Introduction -- 2.2 Characteristic Features of Solid Oxide Fuel Cells -- 2.2.1 Merits and Demerits of SOFCs -- 2.2.2 Issues for Intermediate-Temperature SOFCs -- 2.2.3 Stack Design -- 2.3 Development of Intermediate Temperature SOFC Stacks/Systems -- 2.3.1 Kyocera/Osaka Gas -- 2.3.2 Mitsubishi Materials Corporation -- 2.3.3 Micro SOFCs by TOTO -- 2.4 Perspective -- 2.4.1 Applications -- 2.4.2 Fuel Flexibility and Reliability in Relationship to Intermediate-Temperature SOFCs -- 2.4.3 Hybrid Systems -- 2.5 Summary -- References -- 3 Ionic Conduction in Perovskite-Type Compounds -- 3.1 Introduction -- 3.2 Conduction Behavior of Perovskite-Type Compounds -- 3.3 Early Studies on Ionic Conduction in Perovskite-Type Oxides -- 3.4 Oxide Ion Conduction -- 3.5 Proton Conduction -- 3.6 Lithium Ion Conduction -- 3.7 Halide Ion Conduction -- 3.8 Silver Ion Conduction -- References -- 4 Oxide Ion Conductivity in Perovskite Oxide for SOFC Electrolyte -- 4.1 Introduction -- 4.2 Oxide Ion Conductivity in Oxide -- 4.3 Oxide Ion Conductivity in Perovskite Oxides -- 4.4 LaGaO-Based Oxide Doped with Sr and Mg (LSGM) as a New Oxide Ion Conductor -- 4.4.1 Effects of Dopant for La and Ga Site -- 4.4.2 Transition Metal Doping Effects on Oxide Ion Conductivity in LSGM -- 4.5 Basic Properties of the LSGM Electrolyte System -- 4.5.1 Phase Diagram of La-Sr-Ga-Mg-O -- 4.5.2 Reactivity with SOFC Component -- 4.5.3 Thermal Expansion Behavior and Other Properties -- 4.5.4 Behavior of Minor Carrier -- 4.5.5 Diffusivity of Oxide Ion -- 4.6 Performance of a Single Cell Using LSGM Electrolyte -- 4.7 Preparation of LaGaO Thin-Film Electrolytes for Application at Temperatures Lower Than 773 K -- 4.8 Oxide Ion Conductivity in the Perovskite-Related Oxides -- 4.9 Summary -- References -- 5 Diffusivity of the Oxide Ion in Perovskite Oxides -- 5.1 Introduction -- 5.1.1 Definitions of Diffusion Coefficients -- 5.1.2 The Oxygen Tracer Diffusion Coefficient -- 5.1.3 The Surface Exchange Coefficient -- 5.1.4 Defect Chemistry and Oxygen Transport -- 5.1.5 Defect Equilibria -- 5.2 Diffusion in Mixed Electronic-Ionic Conducting Oxides (MEICs) -- 5.2.1 Effect of A-Site Cation on Oxygen Diffusivity -- 5.2.2 The Effect of B-Site Cation on Oxygen Diffusivity -- 5.2.3 The Effect of A-Site Cation Vacancies on Oxygen Diffusivity -- 5.2.4 Temperature Dependence of the Oxygen Diffusion Coefficient -- 5.2.5 The Effect of Oxygen Pressure -- 5.3 Oxygen Diffusion in Ionic Conducting Perovskites -- 5.4 Oxygen Diffusion in Perovskite-Related Materials -- 5.5 Correlations Between Oxygen Diffusion Parameters -- 5.6 Conclusions -- References -- 6 Structural Disorder, Diffusion Pathway of Mobile Oxide Ions, and Crystal Structure in Perovskite-Type Oxides and Related Materials -- 6.1 Introduction -- 6.2 High-Temperature Neutron Powder Diffractometry -- 6.3 Data Processing for Elucidation of the Diffusion Paths of Mobile Oxide Ions in Ionic Conductors: Rietveld Analysis, Maximum Entropy Method (MEM), and MEM-Based Pattern Fitting |
| Summary |
The continuing development of fuel cells offers promising technologies for the conversion of chemical energy from hydrocarbon fuels into electricity without forming air pollutants. Perovskite Oxides for Solid Oxide Fuel Cells provides insight into the materials aspects of one of the most promising fuel cell types available. Solid Oxide Fuel Cells (SOFCs) have significant advantages over other fuel cell types, such as high efficiency, flexibility in fuel, high reliability, simple balance of plant (BOP) and a long history. Because of these advantages, SOFC technology is attracting a great deal of attention for use in power generation and for its potential in heat generation. Perovskite oxides are widely used for different SOFC components. Detailed description of various aspects of perovskite oxides are presented in this book. Each chapter in the book is written by leading international researchers and covers topics including: General Introduction of SOFC; Perovskite fast oxide ion conductors; High temperature perovskite proton conductors; Perovskite electrode catalyst and catalysis; SOFC stack development using perovskite oxide; The effects of decreasing SOFC operating temperatures to increase reliability, durability and stability. Perovskite Oxides for Solid Oxide Fuel Cells provides comprehensive and up-to-date information on the materials, properties, and performance for SOFCs and is appropriate for researchers and engineers in the field |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Print version record |
| Subject |
Solid oxide fuel cells.
|
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Perovskite (Mineral)
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TECHNOLOGY & ENGINEERING -- Electrical.
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Ingénierie.
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Perovskite (Mineral)
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Solid oxide fuel cells
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| Form |
Electronic book
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| Author |
Ishihara, Tatsumi, 1961-
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| ISBN |
9780387777085 |
|
0387777083 |
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0387777075 |
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9780387777078 |
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1282288474 |
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9781282288478 |
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