| Description |
1 online resource (416 pages) |
| Contents |
Cover -- Title Page -- Copyright -- Contents -- Introduction and Preface -- References -- Chapter 1 Functionalization of Heteroaromatic Substrates using Groups 9 and 10 Catalysts -- 1.1 Introduction -- 1.2 Thiophenes, furans, and Related Heterocycles -- 1.3 Pyrroles, Indoles, Pyridines, and Imidazopyridines -- 1.4 Azoles and Other Miscellaneous Heterocycles -- 1.5 Summary -- References -- Chapter 2 Ruthenium Catalysts for the Alkylation of Functionalized Arenes and Heteroaromatic Substrates via Hydroarylation -- 2.1 Introduction |
|
2.2 Alkylation by Ruthenium(0) Catalysts via Oxidative-Addition C-H Activation2.2.1 Alkylation by Ruthenium(II) Catalysts via Carboxylate-Assisted C-H Activation -- 2.3 Summary and Conclusions -- Abbreviations -- References -- Chapter 3 Alkylation of Arenes Without Chelation Assistance: Transition Metal Catalysts with d6 Electron Configurations -- 3.1 Transition Metal-Mediated Arene Alkylation: Overview -- 3.2 Octahedral d6 Transition Metal Catalysts for Olefin Hydroarylation: Scorpionate Supported Ru(II) Catalysts |
|
3.2.1 Structureâ#x80;#x93;Activity Relationships with TpRu(L)(NCMe)Ph: Examination of Elementary Steps and Catalytic Hydrophenylation of Ethylene as a Function of Ligand L3.2.2 Ethylene Hydrophenylation Catalyzed by Cationic Ru(II) Complexes Ligated by Poly(pyrazolyl)alkanes -- 3.3 Olefin Hydroarylation Catalyzed by Octahedral d6 Ir(III) Supported by the Acetylacetonate Ligand -- 3.3.1 Mechanism of Catalytic Olefin Hydrophenylation using Ir(III) Supported by the Acetylacetonate Ligand -- 3.3.2 Other d6 Ir(III) Catalysts |
|
3.4 Summary: Comparison of Ru(II) and Ir(III) Catalysts for Olefin Hydroarylation3.5 Future Outlook: Extension of Olefin Hydroarylation using Hydrocarbons to Earth Abundant Metals -- References -- Chapter 4 Hydroarylation of Olefins with Complexes Bearing d8 Metal Centers -- 4.1 Introduction -- 4.2 PtII Catalyzed Hydroarylation -- 4.2.1 PtII Hydroarylation Catalysts Bearing Anionic Bidentate (NN) Ligands -- 4.2.2 PtII Hydroarylation Catalysts Bearing Neutral Bidentate (NN) Ligands -- 4.2.3 PtII Hydroarylation Catalysts Supported by Nonnitrogen-based Ligands |
|
4.2.4 Summary of PtII Catalyzed Hydroarylations4.3 RhI-Catalyzed Hydroarylation -- 4.3.1 Reactions of Unfunctionalized Arenes with RhI Complexes Proceeding via Hydroarylation-Like Mechanisms -- 4.3.2 Directed ortho-Hydroarylation Catalyzed by RhI Complexes -- 4.3.3 RhI-Catalyzed Hydroarylation with Fluorinated Arenes -- 4.3.4 Summary of RhI-Catalyzed Hydroarylation -- 4.4 Directed ortho-Hydroarylation Catalyzed by IrI Complexes -- 4.5 Hydroarylation with Ni0 Complexes via NiII Intermediates |
| Notes |
""4.6 Formal Hydroarylation Reactions with PdII Catalysts via Heck-Like Mechanisms"" |
|
Print version record |
| Subject |
Catalysis.
|
|
Catalysis.
|
| Form |
Electronic book
|
| Author |
Gunnoe, T. Brent
|
|
Habgood, Laurel Goj
|
| ISBN |
9783527697632 |
|
3527697632 |
|
