| Description |
1 online resource (478 pages) |
| Contents |
Front Cover; Binary Polar Liquids; Binary Polar Liquids: Structural and Dynamic Characterization Using Spectroscopic Methods; Copyright; Contents; Preface; 1 -- Theoretical and Experimental Aspects of Time Domain Permittivity Spectroscopy; 1.1 INTRODUCTION; 1.1.1 Polar; 1.1.2 Nonpolar; 1.1.3 Dipole Moment; 1.2 POLARIZATION; 1.2.1 Polarization Mechanisms; 1.2.2 Electronic Polarization; 1.2.3 Atomic Polarization; 1.2.4 Orientation Polarization; 1.2.5 Interfacial Polarization; 1.3 DIELECTRIC THEORIES; 1.3.1 Theories of Static Permittivity; 1.3.2 The Debye Theory of Static Permittivity |
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1.3.3 The Onsager Dielectric Theory1.3.4 The Kirkwood Theory; 1.3.5 The Frohlich Theory; 1.4 DYNAMICAL THEORY OF DIELECTRICS; 1.4.1 The Debye Model; 1.4.2 The Cole-Cole Model; 1.4.3 The Cole-Davidson Model; 1.4.4 The Havriliak-Negami Model; 1.4.5 The Double-Debye (Two-Debye) Model; 1.5 DIELECTRIC MODELS RELATED TO MOLECULAR BEHAVIOR; 1.5.1 Kirkwood Correlation Factor; 1.5.2 Kirkwood Correlation Factor in Binary Mixture; 1.5.3 Excess Dielectric Constant; 1.5.4 The Modified Bruggeman Model; 1.5.5 The Redlich-Kister Model23; 1.6 THERMODYNAMIC PARAMETERS; 1.7 EXPERIMENTAL TECHNIQUE |
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1.7.1 Dielectric Relaxation Spectroscopy1.7.2 Basic Principle of TDR; 1.7.3 Sampling Oscilloscope; 1.7.4 Sample Cell; 1.7.5 Choice of Time Window; 1.8 DATA ANALYSIS; 1.8.1 Bilinear Calibration Method; 1.8.2 An Example: Determination of Relaxation Time and Distribution Parameters; 1.9 CONCLUSION; References; 2 -- Dielectric Relaxation in Binary Polar Liquids Containing Alcohols and Molecules With -OH Group; 2.1 INTRODUCTION; 2.2 WATER-METHANOL BINARY SYSTEM; 2.3 THE WATER-ETHANOL SYSTEM; 2.4 THE WATER-PROPANOL SYSTEM; 2.5 THE WATER-ETHYLENE GLYCOL SYSTEM |
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2.6 THE WATER-TERTIARY BUTYL ALCOHOL SYSTEM2.7 THE ETHANOL-ETHYLENE GLYCOL SYSTEM; 2.8 OTHER SIMILAR SYSTEM; 2.9 CONCLUSION; References; 3 -- Spectroscopic Characterization of Binary Polar Liquid Mixtures Containing Amino or Sulfoxide Group and Hydroxyl ... ; 3.1 INTRODUCTION; 3.2 N, N-DIMETHYLAMINOETHANOL-FORMAMIDE BINARY SYSTEM; 3.3 WATER-FORMAMIDE BINARY SYSTEM; 3.4 WATER-N-METHYLFORMAMIDE BINARY SYSTEM; 3.5 WATER-N, N-DIMETHYLFORMAMIDE BINARY SYSTEM; 3.6 2-ETHOXYETHANOL-N, N-DIMETHYLFORMAMIDE BINARY SYSTEM; 3.7 ETHANOL-N, N-DIMETHYLFORMAMIDE BINARY SYSTEM |
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3.8 PROPANOL-N, N-DIMETHYLFORMAMIDE BINARY SYSTEM3.9 ETHANOLAMINE-N, N-DIMETHYLACETAMIDE BINARY SYSTEM; 3.10 WATER-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.11 ETHANOL-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.12 PROPANOL-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.13 2-ETHOXYETHANOL-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.14 ANILINE-DIMETHYLSULFOXIDE BINARY SYSTEM; 3.15 ANILINE-METHANOL BINARY SYSTEM; 3.16 ANILINE-ETHANOL BINARY SYSTEM; 3.17 ANILINE-PROPANOL BINARY SYSTEM; 3.18 ANILINE-BUTANOL BINARY SYSTEM; 3.19 ANILINE-HEXANOL BINARY SYSTEM; 3.20 ANILINE-HEPTANOL BINARY SYSTEM |
| Summary |
Binary Polar Liquids: Structural and Dynamic Characterization Using Spectroscopic Methods provides liquid state physical chemists and physicists with practical theoretical models based on a wealth of robust data that describe the dielectric properties of dipolar materials in a systematic manner. In many applications, reference measurements using dielectric permittivity data are required. Over the past three decades, the author has compiled and analyzed permittivity research data and relaxation times for various polar liquids and their mixtures. The resulting structural data - as determined from various models - is critically evaluated, arming scientists with a complete characterization of the spectra of water-containing mixtures |
| Notes |
3.21 ANILINE-N, N-DIMETHYLFORMAMIDE BINARY SYSTEM |
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Print version record |
| Subject |
Liquid dielectrics.
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TECHNOLOGY & ENGINEERING -- Mechanical.
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Liquid dielectrics
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| Form |
Electronic book
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| Author |
Kumbharkhane, Ashok
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Chaudhari, Ajay
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| ISBN |
9780128132548 |
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012813254X |
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