Description |
1 online resource (x, 206 pages) : illustrations |
Series |
Topics in organometallic chemistry, 1436-6002 ; 24 |
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Topics in organometallic chemistry ; 24. 1436-6002
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Contents |
Catalytic addition of C--H bonds to C--C multiple bonds / F. Kakiuchi -- Chelation-assisted arylation via C--H bond cleavage / L. Ackermann -- Catalytic arylation and vinylation reactions directed by anionic oxygen functions via cleavage of C--H and C--C bonds / T. Satoh [and others] -- Chelate-directed oxidative functionalization of carbon-hydrogen bonds: synthetic applications and mechanistic insights / D. Kalyani [and others] -- Directed C--C bond activation by transition metal complexes / C.-H. Jun [and others] -- Directed rhodium-catalyzed hydroformylation of alkenes / B. Breitreit -- Directed Mizoroki-Heck reactions / M. Oestreich |
Summary |
Directed metalation is recognized as one of the most useful methodologies for the regio- and stereoselective generation of organometallic species, the generation of which necessarily leads to the selective formation of organic products. Cyclometalation using Li, Mn, and Pd, and directed hydrometalation and carbometalation using Al and Zn, have been utilized for regio- and/or stereoselective synthesis for decades. Recently, a new chelation-assisted methodology has been developed not only for controlling regio- and stereoselectivity of reactions, but also for accelerating reactions. In particula |
Analysis |
chemie |
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chemistry |
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geneeskunde |
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medicine |
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organometaalverbindingen |
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organometallic compounds |
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katalyse |
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catalysis |
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anorganische scheikunde |
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inorganic chemistry |
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Chemistry (General) |
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Chemie (algemeen) |
Bibliography |
Includes bibliographical references and index |
Notes |
Print version record |
In |
Springer e-books |
Subject |
Metal catalysts.
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Organometallic chemistry.
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Chimie.
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Science des matériaux.
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Metal catalysts
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Organometallic chemistry
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Form |
Electronic book
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Author |
Chatani, Naoto
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Ackermann, L. (Lutz)
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ISBN |
9783540758099 |
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3540758097 |
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9783540758082 |
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3540758089 |
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9786611115487 |
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661111548X |
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