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Title Directed metallation / volume editor, Naoto Chatani ; with contributions by L. Ackermann [and others]
Published Berlin, Germany : Springer Verlag, 2007

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Description 1 online resource (x, 206 pages) : illustrations
Series Topics in organometallic chemistry, 1436-6002 ; 24
Topics in organometallic chemistry ; 24. 1436-6002
Contents Catalytic addition of C--H bonds to C--C multiple bonds / F. Kakiuchi -- Chelation-assisted arylation via C--H bond cleavage / L. Ackermann -- Catalytic arylation and vinylation reactions directed by anionic oxygen functions via cleavage of C--H and C--C bonds / T. Satoh [and others] -- Chelate-directed oxidative functionalization of carbon-hydrogen bonds: synthetic applications and mechanistic insights / D. Kalyani [and others] -- Directed C--C bond activation by transition metal complexes / C.-H. Jun [and others] -- Directed rhodium-catalyzed hydroformylation of alkenes / B. Breitreit -- Directed Mizoroki-Heck reactions / M. Oestreich
Summary Directed metalation is recognized as one of the most useful methodologies for the regio- and stereoselective generation of organometallic species, the generation of which necessarily leads to the selective formation of organic products. Cyclometalation using Li, Mn, and Pd, and directed hydrometalation and carbometalation using Al and Zn, have been utilized for regio- and/or stereoselective synthesis for decades. Recently, a new chelation-assisted methodology has been developed not only for controlling regio- and stereoselectivity of reactions, but also for accelerating reactions. In particula
Analysis chemie
chemistry
geneeskunde
medicine
organometaalverbindingen
organometallic compounds
katalyse
catalysis
anorganische scheikunde
inorganic chemistry
Chemistry (General)
Chemie (algemeen)
Bibliography Includes bibliographical references and index
Notes Print version record
In Springer e-books
Subject Metal catalysts.
Organometallic chemistry.
Chimie.
Science des matériaux.
Metal catalysts
Organometallic chemistry
Form Electronic book
Author Chatani, Naoto
Ackermann, L. (Lutz)
ISBN 9783540758099
3540758097
9783540758082
3540758089
9786611115487
661111548X