Title Organo-di-metallic compounds (or reagents) : synergistic effects and synthetic applications / Zhenfeng Xi, editor ; with contributions by G. Barrozzino-Consiglio ... [and more]

Published Cham : Springer, 2014

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Description 1 online resource (vii, 205 pages) : illustrations (some color) Series Topics in Organometallic Chemistry, 1436-6002 ; 47 Topics in organometallic chemistry ; 47. 1436-6002 Contents 880-01 Organo-di-Lithio Reagents: Cooperative Effect and Synthetic Applications -- New Formulas for Zincate Chemistry: Synergistic Effect and Synthetic Applications of Hetero-bimetal Ate Complexes -- FascinATES: Mixed-metal ate compounds that function synergistically -- Transmetallation of Zirconacycles to Other Metals for Organic Synthesis -- [Li, Li]-Mixed Aggregates: Synergy Between Chiral Lithium Amides and Methyllithium or Butyllithium -- Organometallic Chemistry with Dianionic Pincer Ligands -- Geminal Dianions as Precursors of Carbene Complexes 880-01/(S Intro; Preface; Contents; Organo-di-Lithio Reagents: Cooperative Effect and Synthetic Applications; 1 Introduction; 2 Preparation and Structures of 1,4-Dilithio-1,3-Butadienes; 3 Intramolecular Reaction Pattern: Formation of α-Lithio Siloles from Silyl-Substituted Di-lithio Reagents via E/Z Isomerizati ... ; 3.1 Reaction and Mechanistic Aspects; 3.2 Synthetic Applications; 4 Intermolecular Reaction Pattern; 4.1 Reactions with Carbonyl Compounds: Formation of Cyclopentadiene or 2,5-Dihydrofuran Derivatives Summary The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors Analysis chemie chemistry organometaalverbindingen organometallic compounds katalyse catalysis Chemistry (General) Chemie (algemeen) Notes Includes index Online resource; title from PDF title page (SpringerLink, viewed September 24, 2014) Subject Organometallic compounds -- Synthesis Organometallic compounds -- Synthesis Form Electronic book Author Xi, Zhenfeng, editor Barozzino-Consiglio, Gabriella ISBN 9783319084282 3319084283 3319084275 9783319084275

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