| Description |
1 online resource (608 pages) |
| Contents |
Machine generated contents note: 1. Introduction / Yurii Sh. Matros -- 1.1. Periodic Operation -- 1.2. Origins of Periodic Operation -- 1.3. Variables in Periodic Operation -- 1.4. Cycle Structure in Periodic Operation -- 1.5. Measuring Improvement -- 1.6. Inherently Periodic Processes -- 1.7. Objectives of Periodic Operation -- 1.8. Strategies in Periodic Operation -- 1.9. Equipment for Periodic Operation -- 1.10. Reaction Systems Examined -- 1.11. New Directions -- 1.12.A Brief History of the Study of Periodic Operation -- 2. Hydrogenation Processes / Peter Lewis Silveston -- 2.1. Ammonia Synthesis -- 2.2. NOx Reduction -- 2.3. Methanation -- 2.4. Methanol Synthesis -- 2.5. Ethylene Hydrogenation -- 2.6. Aromatics Hydrogenation -- 2.7. Oscillatory Behavior -- 3. Catalytic Oxidation and Reduction of Gases / Albert Renken -- 3.1. Introduction -- 3.2. CO Oxidation -- 3.3. Sulfur Dioxide Oxidation -- 3.4. Reduction of SO3 by CO Over Platinum -- 3.5. Reduction of Nitrogen Oxides -- 3.6. Traveling Waves in Packed Beds -- 4. Partial Oxidation and Dehydrogenation of Hydrocarbons / Adesoji A. Adesina -- 4.1. Introduction -- 4.2. Partial Oxidation and Reforming of Methane to Syngas -- 4.3. Oxidative Coupling of Methane -- 4.4. Epoxidation -- 4.5. Propene and Butene Partial Oxidation and Ammoxidation -- 4.6. Catalytic Dehydrogenation of Propane, Butane and Higher Hydrocarbons -- 4.7. Maleic Anhydride from Butane -- 4.8. Anhydrides and Aldehydes from Aromatic Hydrocarbons -- 4.9. Aromatic Nitriles -- 5.Combustion Systems / Robert Ross Hudgins -- 5.1. Non-Catalytic Combustion Reactions -- 5.2. Catalytic Combustion -- 5.3. Looping Combustion -- 5.4. Simulated Loop Reactors -- 6. Automotive Exhaust Catalysis / William S. Epling -- 6.1. Internal Combustion Engines -- 6.2. Modulation of Detoxification Reactions -- 6.3. Modeling Studies -- 6.4. Studies on Modulating Automotive Exhaust -- 6.5. Effect of A/F Modulation on Poisoning and Sintering -- 6.6. Effects of Irregular A/F Variation -- 6.7. Lean Burn Spark-Ignited Engines -- 6.8. Application of NSR to Diesel Exhausts -- 6.9. Does A/F Modulation Improve Converter Performance? -- 7. Polymerization Under Modulation / Peter L. Silveston -- 7.1. Introduction -- 7.2. Simulation of Polymerization Under Input Modulation -- 7.3. Experiments on Polymerization Under Input Modulation -- 7.4. Spontaneous Oscillations -- 7.5. Saturation of Polymers -- 7.6. Assessment -- 8. Catalytic Gas-Solid Reactions / Peter Lewis Silveston -- 8.1. Partial Oxidation and Oxidative Dehydrogenation of Hydrocarbons -- 8.2. Methane Cracking -- 8.3. Non-Catalytic Gas-Solid Reactions -- 8.4. Catalytic Gasification Under Modulation -- 8.5. Gasification Employing a Circulating Solid Oxygen Carrier -- 8.6.Combustion in Circulating Fluidized Beds -- 8.7. Periodic Reaction Switching -- 9. Electrochemical Processes / Peter Lewis Silveston -- 9.1. Introduction -- 9.2. Electroplating -- 9.3. Electroforming -- 9.4. Anodization -- 9.5. Electrochemical Machining and Polishing -- 9.6. Electrowinning and Electrorefining -- 9.7. Galvanic Cells -- 9.8. Electrolytic Production of Chemicals -- 9.9. Applicability of Principles or Practices to Non-Electrochemical Reactions -- 10. Modulation of Biological Processes / Jeno M. Scharer -- 10.1. Introduction -- 10.2. Theoretical Considerations -- 10.3. Substrate and Flow Rate Modulation -- 10.4. Dissolved Oxygen Modulation -- 10.5. Culture Medium Tuning -- 10.6. Survival in Mixed Cultures -- 10.7. Stabilization of Recombinant Cell Cultures -- 10.8. Applications to Immobilized Cells or Enzymes -- 10.9. Fed-Batch Operations -- 10.10. Overview -- 11. Miscellaneous Reactions / Albert Renken -- 11.1. Ethyl Acetate from Ethylene and Acetic Acid -- 11.2. Claus Reaction -- 11.3. Dehydrogenation of Methanol -- 11.4. Deamination and Alcohol Dehydration Reactions -- 11.5. Photocatalytic Degradation of AZO Dyes -- 11.6. The Minimal Bromate Reaction -- 11.7. Propanol Dehydrogenation -- 11.8. Glucose Oxidation -- 11.9. Overview -- 12. Modulation of Multiple Reactions / Albert Renken -- 12.1. Introduction -- 12.2. Homogeneous Reactions -- 12.3. Solids Catalyzed Reactions -- 12.4.Competitive Reactions -- 12.5. Methane Homologation -- 12.6. Oligomerization of Ethene -- 12.7. Modulation of Multiple Inputs -- 13. Use of Modulation in Mechanistic Studies / Peter Lewis Silveston -- 13.1. Introduction -- 13.2. Qualitative Applications -- 13.3. Quantitative Applications -- 13.4. Modulation of Light Intensity -- 13.5. Application of Modulation to the Testing of Rival Models -- 13.6. Overview -- 14. Evaluation of Periodic Processes / Andreas Seidel-Morgenstern -- 14.1. Introduction -- 14.2. Nonlinear Frequency Response and Higher Order Frequency Response Functions -- 14.3. Estimation of the Time Average Performance of Periodic Processes Using Nonlinear Frequency Response Analysis -- 14.4. Application of Nonlinear Frequency Response Analysis for the Estimation of the Periodic Steady States of Cyclic Processes -- 14.5. Summary -- 15. Pressure Modulation / Robert Ross Hudgins -- 15.1. Introduction -- 15.2. Acceleration of Mass Transfer -- 15.3. Sonocatalysis -- 15.4. Periodic Pressure Reduction -- 15.5.Combined Compression and Reaction -- 15.6. Application to Rate and Equilibrium Measurements -- 15.7. Assessment and Research Opportunities -- 16. Temperature Modulation / Robert Ross Hudgins -- 16.1. Introduction -- 16.2. Theoretical Studies -- 16.3. Simulation Studies -- 16.4. Experimental Studies with Conventional Laboratory Equipment -- 16.5. Temperature Modulation of Trickle Beds -- 16.6. Experimental Studies with Microreactors -- 16.7. Overview and Comments -- 17. Flow Interruption in Trickle Beds / Peter Lewis Silveston -- 17.1. Introduction -- 17.2. Steady-State Operation of a Trickle Bed Reactor -- 17.3. Periodic Operation of Trickle Bed Reactors -- 17.4. Liquid Flow Modulation with Multiple Reactions -- 17.5. Hydrodynamics Under Liquid Flow Modulation -- 17.6. Modeling of the Periodic Operation of Trickle Bed Reactors -- 17.7. Summary -- 18. Periodic Flow Reversal / Hristo Sapoundjiev -- 18.1. The Heat-Trapping Concept -- 18.2. Theoretical Aspects -- 18.3. Oxidation of Volatile Organic Compounds -- 18.4. Other Applications of Reverse Flow Reactors -- 18.5. Thermal Reactors -- 18.6. Endothermic Processes -- 18.7. Mass Trapping Reactors -- 18.8. Biofilters -- 18.9. Miscellaneous Applications -- 18.10.Commercial Applications -- 19. Control of Periodically Operated Reactors / Peter Lewis Silveston -- 19.1. Formulation of an Optimal Control Problem for a Periodically Operated Reactor -- 19.2. Chattering Controls -- 19.3. Controls for Stirred Slurry and Fluidized Bed Reactors -- 19.4. Controls for Packed Bed Reactors -- 19.5. Control of Packed Bed Reactors with Flow-Direction Switching -- 19.6. Control of Simulated Moving Bed Chromatographic Reactors -- 19.7. Other Control Schemes for Periodically Operated Reactors -- 19.8.Comments and Research Needs -- 20. Chromatographic Reactors / Motoaki Kawase -- 20.1. Introduction -- 20.2. Concept and Types -- 20.3. General Models -- 20.4. Cyclic Steady State -- 20.5. Pulse Chromatographic Reactor -- 20.6. Countercurrent Moving Bed Chromatographic Reactor -- 20.7. Continuous Rotating Annular Chromatographic Reactor -- 20.8. Stepwise, Countercurrent Multi-Stage Fluidized Bed Chromatographic Reactor -- 20.9. Fixed Bed Chromatographic Reactor With Flow Direction Switching -- 20.10. Extractive Reactor Systems -- 20.11. Centrifugal Partition Chromatographic Reactor -- 21. Simulated Moving Bed Chromatographic Reactors / Peter Lewis Silveston -- 21.1. Operation and Application -- 21.2. Modeling and Simulation -- 21.3. Experimental Studies -- 21.4. Other Reactor Applications of Simulated Moving Beds -- 22. Pressure and Temperature Swing Reactors / Peter Lewis Silveston -- 22.1. Concepts and Types of Pressure Swing Reactors -- 22.2. Models for Swing Reactors -- 22.3.Computational Considerations -- 22.4 |
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Simulations of Pressure Swing Systems -- 22.5. Experimental Studies -- 22.6. Temperature Swing Reactors -- 22.7. Simulation of Temperature Swing Systems -- 22.8. Temperature Swing Reactor Networks -- 22.9. Experimental -- 22.10.Combined Pressure and Temperature Swing Reactors -- 22.11. Overview and Assessment -- 23. New Directions -- Research and Development Challenges / Peter Lewis Silveston -- 23.1. Challenges -- 23.2. New Directions |
| Summary |
This comprehensive review, prepared by 24 experts, many of whom are pioneers of the subject, brings together in one place over 40 years of research in this unique publication. This book will assist R & D specialists, research chemists, chemical engineers or process managers harnessing periodic operations to improve their process plant performance. Periodic Operation of Reactors covers process fundamentals, research equipment and methods and provides "the state of the art" for the periodic operation of many industrially important catalytic reactions. Emphasis is on experimental results, modeling and simulation. Combined reaction and separation are dealt with, including simulated moving bed chromatographic, pressure and temperature swing and circulating bed reactors. Thus, Periodic Operation of Reactors offers readers a single comprehensive source for the broad and diverse new subject. This exciting new publication is a "must have" for any professional working in chemical process research and development. Key features: Provides the only comprehensive reference on the fundamentals, development and applications of periodic reactor operation, using contributions from the research pioneers. This authoritative reference focuses on applications helping readers to use this book to deliver results in their own work. Complete literature references will be an invaluable assistance for readers collecting data and models from past research. About the editors: Peter L. Silveston is a Distinguished Professor Emeritus at the University of Waterloo in Canada. Professor Silveston has authored or co-authored three previous books on reactor engineering topics as well as close to 300 research publications. He is a graduate of M.I.T. and the Technical University of Munich (Germany). Robert Hudgins is a Professor Emeritus at the University of Waterloo. His research interests are reactor engineering, specifically periodic operation of catalytic reactors, and he has about 250 research publications. He is a graduate of the University of Toronto and Princeton University. FEATURE: A comprehensive reference on the fundamentals, development and applications of periodic operation. BENEFIT: Provides readers with a single comprehensive source for this extremely broad and diverse subject FEATURE: Contributors and editors include the pioneers of the subject as well as the leading researchers in the field. BENEFIT: Has the authority and experience of the leading players in the field FEATURE: Covers both fundamentals and the state of the art for each operation scenario, and brings all types of periodic operation together in a single volume. BENEFIT: Provides a succinct reference to the most important applications in the filed, allowing readers to understand how to apply techniques or technologies to their own situation FEATURE: Discussion is focused on experimental results rather than theoretical ones; provides a rich source of experimental data, plus process models. BENEFIT: Applied approach that is geared helping practicing engineers and researchers solve problems FEATURE: Accompanying website with modelling data BENEFIT: Engineers can engage with experimental and actual performance data |
| Bibliography |
Includes bibliographical references and index |
| Notes |
Print version record |
| Subject |
Chemical reactors.
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Chemical reactors
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| Form |
Electronic book
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| Author |
Hudgins, R. R
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