| Description |
1 online resource (531 p.) |
| Contents |
Cover -- Title Page -- Copyright Page -- Contents -- List of Contributors -- Preface -- Chapter 1 Introduction to Atomically Precise Nanochemistry -- 1.1 Why Atomically Precise Nanochemistry? -- 1.1.1 Motivations from Nanoscience Research -- 1.1.2 Motivations from Inorganic Chemistry Research -- 1.1.3 Motivations from Gas Phase Cluster Research -- 1.1.4 Motivations from Other Areas -- 1.2 Types of Nanoclusters Covered in This Book -- 1.2.1 Atomically Precise Metal Nanoclusters (Au, Ag, Cu, Ni, Rh) -- 1.2.2 Endohedral Fullerenes and Graphene Nanoribbons -- 1.2.3 Zintl Clusters |
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1.2.4 Metal-Oxo Nanoclusters -- 1.3 Some Fundamental Aspects -- 1.3.1 Synthesis and Crystallization -- 1.3.2 Structural and Bonding Patterns -- 1.3.3 Transition from Nonmetallic to Metallic State: Emergence of Plasmon -- 1.3.4 Transition from Metal Complexes to the Cluster State: Emergence of Core -- 1.3.5 Doping and Alloying -- 1.3.6 Redox and Magnetism -- 1.3.7 Energy Gap Engineering -- 1.3.8 Assembly of Atomically Precise Nanoclusters -- 1.4 Some Applications -- 1.4.1 Chemical and Biological Sensing -- 1.4.2 Biomedical Imaging, Drug Delivery, and Therapy -- 1.4.3 Antibacteria |
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1.4.4 Solar Energy Conversion -- 1.4.5 Catalysis -- 1.5 Concluding Remarks -- Acknowledgment -- References -- Chapter 2 Total Synthesis of Thiolate-Protected Noble Metal Nanoclusters -- 2.1 Introduction -- 2.2 Size Engineering of Metal Nanoclusters -- 2.2.1 Size Engineering by Reduction-Growth Strategy -- 2.2.2 Size Engineering by Size Conversion Strategy -- 2.3 Composition Engineering of Metal Nanoclusters -- 2.3.1 Metal Composition Engineering -- 2.3.2 Ligand Composition Engineering -- 2.4 Structure Engineering of Metal Nanoclusters -- 2.4.1 Pseudo-Isomerization -- 2.4.2 Isomerization |
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2.5 Top-Down Etching Reaction of Metal Nanoclusters -- 2.6 Conclusion and Outlooks -- Contributions -- References -- Chapter 3 Thiolated Gold Nanoclusters with Well-Defined Compositions and Structures -- 3.1 Introduction -- 3.2 Synthesis, Purification, and Characterization of Gold Nanoclusters -- 3.2.1 Synthesis -- 3.2.1.1 Synthesis Strategy -- 3.2.1.2 Gold Salt (Complex) Reduction Method -- 3.2.1.3 Ligand Induction Method -- 3.2.1.4 Anti-Galvanic Reaction Method -- 3.2.2 Isolation and Purification -- 3.2.3 Characterization -- 3.3 Structures of Gold Nanoclusters |
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3.3.1 Kernel Structures of Aun(SR)m -- 3.3.2 Kernels Based on Tetrahedral Au4 Units -- 3.3.2.1 Kernels in fcc Structure -- 3.3.2.2 Kernels Arranged in hcp and bcc Fashions -- 3.3.2.3 Kernels in Mirror Symmetry and Dual-Packing (fcc and non-fcc) -- 3.3.2.4 Kernels Based on Icosahedral Au13 Unit -- 3.3.2.5 Kernels with Multiple Shells -- 3.3.3 Protecting Surface Motifs of Aun(SR)m Clusters -- 3.3.3.1 Staple-like Aux(SR)x+1 (x = 1, 2, 3, 4, 8) motifs -- 3.3.3.2 Ring-like Aux(SR)x (x = 4, 5, 6, 8) Motifs -- 3.3.3.3 Giant Au20S3(SR)18 and Au23S4(SR)18 Staple Motifs |
| Notes |
Description based upon print version of record |
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3.3.3.4 Homo-Kernel Hetero-Staples |
| Bibliography |
References -- Chapter 3 Thiolated Gold Nanoclusters with Well-Defined Compositions and Structures -- 3.1 Introduction -- 3.2 Synthesis, Purification, and Characterization of Gold Nanoclusters -- 3.2.1 Synthesis -- 3.2.1.1 Synthesis Strategy -- 3.2.1.2 Gold Salt (Complex) Reduction Method -- 3.2.1.3 Ligand Induction Method -- 3.2.1.4 Anti-Galvanic Reaction Method -- 3.2.2 Isolation and Purification -- 3.2.3 Characterization -- 3.3 Structures of Gold Nanoclusters -- 3.3.1 Kernel Structures of Aun(SR)m -- 3.3.2 Kernels Based on Tetrahedral Au4 Units -- 3.3.2.1 Kernels in fcc Structure -- 3.3.2.2 Kernels Arranged in hcp and bcc Fashions -- 3.3.2.3 Kernels in Mirror Symmetry and Dual-Packing (fcc and non-fcc) -- 3.3.2.4 Kernels Based on Icosahedral Au13 Unit -- 3.3.2.5 Kernels with Multiple Shells -- 3.3.3 Protecting Surface Motifs of Aun(SR)m Clusters -- 3.3.3.1 Staple-like Aux(SR)x+1 (x = 1, 2, 3, 4, 8) motifs -- 3.3.3.2 Ring-like Aux(SR)x (x = 4, 5, 6, 8) Motifs -- 3.3.3.3 Giant Au20S3(SR)18 and Au23S4(SR)18 Staple Motifs -- 3.3.3.4 Homo-Kernel Hetero-Staples -- 3.4 Properties and Applications -- 3.4.1 Properties -- 3.4.1.1 Optical Absorption -- 3.4.1.2 Photoluminescence -- 3.4.1.3 Chirality -- 3.4.1.4 Magnetism -- 3.4.2 Applications -- 3.4.2.1 Sensing -- 3.4.2.2 Biological Labeling and Biomedicine -- 3.4.2.3 Catalysis -- 3.5 Conclusion and Future Perspectives -- Acknowledgments -- References -- Chapter 4 Structural Design of Thiolate-Protected Gold Nanoclusters -- 4.1 Introduction -- 4.2 Structural Design Based on "Divide and Protect" Rule -- 4.2.1 A Brief Introduction of the Idea -- 4.2.2 Atomic Structure of Au68(SH)32 -- 4.2.3 Atomic Structure of Au68(SH)34 -- 4.3 Structural Design via Redistributing the "Staple" Motifs on the Known Au Core Structures -- 4.3.1 A Brief Introduction of the Idea -- 4.3.2 Atomic Structure of Au22(SH)17 |
| Form |
Electronic book
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| Author |
Jiang, De-en
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| ISBN |
9781119788683 |
|
1119788684 |
|
1119788676 |
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9781119788676 |
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