| Description |
xxii, 826 pages : illustrations (some color) ; 29 cm |
| Contents |
Contents note continued: 11.2.Mass Balance Approach for Multiple Equilibria -- 11.3.Effect of Complexation on Solubility: Conditional Solubility Product -- 11.4.Precipitation Titrations -- ch. 12 Electrochemical Cells and Electrode Potentials -- 12.1.What Are Redox Reactions? -- 12.2.Electrochemical Cells-What Electroanalytical Chemists Use -- 12.3.Nernst Equation-Effects of Concentrations on Potentials -- 12.4.Formal Potential-Use It for Defined Nonstandard Solution Conditions -- 12.5.Limitations of Electrode Potentials -- ch. 13 Potentiometric Electrodes and Potentiometry -- 13.1.Metal Electrodes for Measuring the Metal Cation -- 13.2.Metal-Metal Salt Electrodes for Measuring the Salt Anion -- 13.3.Redox Electrodes-Inert Metals -- 13.4.Voltaic Cells without Liquid Junction-For Maximum Accuracy -- 13.5.Voltaic Cells with Liquid Junction-The Practical Kind -- 13.6.Reference Electrodes: The Saturated Calomel Electrode -- 13.7.Measurement of Potential -- |
|
Contents note continued: 13.8.Determination of Concentrations from Potential Measurements -- 13.9.Residual Liquid-Junction Potential-It Should Be Minimized -- 13.10.Accuracy of Direct Potentiometric Measurements-Voltage Error versus Activity Error -- 13.11.Glass pH Electrode-Workhorse of Chemists -- 13.12.Standard Buffers-Reference for pH Measurements -- 13.13.Accuracy of pH Measurements -- 13.14.Using the pH Meter-How Does It Work? -- 13.15.pH Measurement of Blood-Temperature Is Important -- 13.16.pH Measurements in Nonaqueous Solvents -- 13.17.Ion-Selective Electrodes -- 13.18.Chemical Analysis on Mars using Ion-Selective Electrodes -- ch. 14 Redox and Potentiometric Titrations -- 14.1.First: Balance the Reduction-Oxidation Reaction -- 14.2.Calculation of the Equilibrium Constant of a Reaction-Needed to Calculate Equivalence Point Potentials -- 14.3.Calculating Redox Titration Curves -- 14.4.Visual Detection of the End Point -- |
|
Contents note continued: 14.5.Titrations Involving Iodine: Iodimetry and Iodometry -- 14.6.Titrations with Other Oxidizing Agents -- 14.7.Titrations with Other Reducing Agents -- 14.8.Preparing the Solution-Getting the Analyte in the Right Oxidation State before Titration -- 14.9.Potentiometric Titrations (Indirect Potentiometry) -- ch. 15 Voltammetry and Electrochemical Sensors -- 15.1.Voltammetry -- 15.2.Amperometric Electrodes-Measurement of Oxygen -- 15.3.Electrochemical Sensors: Chemically Modified Electrodes -- 15.4.Ultramicroelectrodes -- 15.5.Microfabricated Electrochemical Sensors -- 15.6.Micro and Ultramicroelectrode Arrays -- ch. 16 Spectrochemical Methods -- 16.1.Interaction of Electromagnetic Radiation with Matter -- 16.2.Electronic Spectra and Molecular Structure -- 16.3.Infrared Absorption and Molecular Structure -- 16.4.Near-Infrared Spectrometry for Nondestructive Testing -- 16.5.Spectral Databases-Identifying Unknowns -- 16.6.Solvents for Spectrometry -- |
|
Contents note continued: 16.7.Quantitative Calculations -- 16.8.Spectrometric Instrumentation -- 16.9.Types of Instruments -- 16.10.Array Spectrometers-Getting the Entire Spectrum at Once -- 16.11.Fourier Transform Infrared Spectrometers -- 16.12.Near-IR Instruments -- 16.13.Spectrometric Error in Measurements -- 16.14.Deviation from Beer's Law -- 16.15.Fluorometry -- 16.16.Chemiluminescence -- 16.17.Fiber-Optic Sensors -- ch. 17 Atomic Spectrometric Methods -- 17.1.Principles: Distribution between Ground and Excited States-Most Atoms Are in the Ground State -- 17.2.Flame Emission Spectrometry -- 17.3.Atomic Absorption Spectrometry -- 17.4.Sample Preparation-Sometimes Minimal -- 17.5.Internal Standard and Standard Addition Calibration -- 17.6.Atomic Emission Spectrometry: The Induction Coupled Plasma (ICP) -- 17.7.Atomic Fluorescence Spectrometry -- ch. 18 Sample Preparation: Solvent and Solid-Phase Extraction -- 18.1.Distribution Coefficient -- 18.2.Distribution Ratio -- |
|
Contents note continued: 18.3.Percent Extracted -- 18.4.Solvent Extraction of Metals -- 18.5.Accelerated and Microwave-Assisted Extraction -- 18.6.Solid-Phase Extraction -- 18.7.Microextraction -- 18.8.Solid-Phase Nanoextraction (SPNE) -- ch. 19 Chromatography: Principles and Theory -- 19.1.Countercurrent Extraction: The Predecessor to Modern Liquid Chromatography -- 19.2.Principles of Chromatographic Separations -- 19.3.Classification of Chromatographic Techniques -- 19.4.Theory of Column Efficiency in Chromatography -- 19.5.Chromatography Simulation Software -- ch. 20 Gas Chromatography -- 20.1.Performing GC Separations -- 20.2.Gas Chromatography Columns -- 20.3.Gas Chromatography Detectors -- 20.4.Temperature Selection -- 20.5.Quantitative Measurements -- 20.6.Headspace Analysis -- 20.7.Thermal Desorption -- 20.8.Purging and Trapping -- 20.9.Small and Fast -- 20.10.Separation of Chiral Compounds -- 20.11.Two-Dimensional GC -- ch. 21 Liquid Chromatography and Electrophoresis -- |
|
Contents note continued: 21.1.High-Performance Liquid Chromatography -- 21.2.Stationary Phases in HPLC -- 21.3.Equipment for HPLC -- 21.4.Ion Chromatography -- 21.5.HPLC Method Development -- 21.6.UHPLC and Fast LC -- 21.7.Open Tubular Liquid Chromatography (OTLC) -- 21.8.Thin-Layer Chromatography -- 21.9.Electrophoresis -- 21.10.Capillary Electrophoresis -- 21.11.Electrophoresis Related Techniques -- ch. 22 Mass Spectrometry -- 22.1.Principles of Mass Spectrometry -- 22.2.Inlets and Ionization Sources -- 22.3.Gas Chromatography-Mass Spectrometry -- 22.4.Liquid Chromatography-Mass Spectrometry -- 22.5.Laser Desorption/Ionization -- 22.6.Secondary Ion Mass Spectrometry -- 22.7.Inductively Coupled Plasma-Mass Spectrometry -- 22.8.Mass Analyzers and Detectors -- 22.9.Hybrid Instruments and Tandem Mass Spectrometry -- ch. 23 Hinetic Methods of Analysis -- 23.1.Kinetics-The Basics -- 23.2.Catalysis -- 23.3.Enzyme Catalysis -- ch. 24 Automation in Measurements -- |
|
Contents note continued: 24.1.Principles of Automation -- 24.2.Automated Instruments: Process Control -- 24.3.Automatic Instruments -- 24.4.Flow Injection Analysis -- 24.5.Sequential Injection Analysis -- 24.6.Laboratory Information Management Systems -- Available on textbook website: www.wiley.com/college/christian -- ch. 25 Clinical Chemistry -- 25.1.Composition of Blood -- 25.2.Collection and Preservation of Samples -- 25.3.Clinical Analysis-Common Determinations -- 25.4.Immunoassay -- Available on textbook website: www.wiley.com/college/christian -- ch. 26 Environmental Sampling and Analysis -- 26.1.Getting a Meaningful Sample -- 26.2.Air Sample Collection and Analysis -- 26.3.Water Sample Collection and Analysis -- 26.4.Soil and Sediment Sampling -- 26.5.Sample Preparation for Trace Organics -- 26.6.Contaminated Land Sites-What Needs to Be Analyzed? -- 26.7.EPA Methods and Performance-Based Analyses -- Available on textbook website: www.wiley.com/college/christian -- |
|
Contents note continued: 3.20.Use of Spreadsheets in Analytical Chemistry -- 3.21.Using Spreadsheets for Plotting Calibration Curves -- 3.22.Slope, Intercept, and Coefficient of Determination -- 3.23.LINEST for Additional Statistics -- 3.24.Statistics Software Packages -- ch. 4 Good Laboratory Practice: Quality Assurance and Method Validation -- 4.1.What Is Good Laboratory Practice? -- 4.2.Validation of Analytical Methods -- 4.3.Quality Assurance-Does the Method Still Work? -- 4.4.Laboratory Accreditation -- 4.5.Electronic Records and Electronic Signatures: 21 CFR, Part 11 -- 4.6.Some Official Organizations -- ch. 5 Stoichiometric Calculations: The Workhorse of the Analyst -- 5.1.Review of the Fundamentals -- 5.2.How Do We Express Concentrations of Solutions? -- 5.3.Expressions of Analytical Results-So Many Ways -- 5.4.Volumetric Analysis: How Do We Make Stoichiometric Calculations? -- 5.5.Volumetric Calculations-Let's Use Molarity -- |
|
Contents note continued: 5.6.Titer-How to Make Rapid Routine Calculations -- 5.7.Weight Relationships-You Need These for Gravimetric Calculations -- ch. 6 General Concepts of Chemical Equilibrium -- 6.1.Chemical Reactions: The Rate Concept -- 6.2.Types of Equilibria -- 6.3.Gibbs Free Energy and the Equilibrium Constant -- 6.4.Le Chatelier's Principle -- 6.5.Temperature Effects on Equilibrium Constants -- 6.6.Pressure Effects on Equilibria -- 6.7.Concentration Effects on Equilibria -- 6.8.Catalysts -- 6.9.Completeness of Reactions -- 6.10.Equilibrium Constants for Dissociating or Combining Species-Weak Electrolytes and Precipitates -- 6.11.Calculations Using Equilibrium Constants-Composition at Equilibrium? -- 6.12.The Common Ion Effect-Shifting the Equilibrium -- 6.13.Systematic Approach to Equilibrium Calculations-How to Solve Any Equilibrium Problem -- 6.14.Some Hints for Applying the Systematic Approach for Equilibrium Calculations -- |
|
Contents note continued: 6.15.Heterogeneous Equilibria-Solids Don't Count -- 6.16.Activity and Activity Coefficients-Concentration Is Not the Whole Story -- 6.17.The Diverse Ion Effect: The Thermodynamic Equilibrium Constant and Activity Coefficients -- ch. 7 Acid-Base Equilibria -- 7.1.The Early History of Acid-Base Concepts -- 7.2.Acid-Base Theories-Not All Are Created Equal -- 7.3.Acid-Base Equilibria in Water -- 7.4.The pH Scale -- 7.5.pH at Elevated Temperatures: Blood pH -- 7.6.Weak Acids and Bases-What Is the pH? -- 7.7.Salts of Weak Acids and Bases-They Aren't Neutral -- 7.8.Buffers-Keeping the pH Constant (or Nearly So) -- 7.9.Polyprotic Acids and Their Salts -- 7.10.Ladder Diagrams -- 7.11.Fractions of Dissociating Species at a Given pH: a Values-How Much of Each Species? -- 7.12.Salts of Polyprotic Acids-Acid, Base, or Both? -- 7.13.Physiological Buffers-They Keep You Alive -- 7.14.Buffers for Biological and Clinical Measurements -- |
|
Contents note continued: 7.15.Diverse Ion Effect on Acids and Bases: cKa and cKb-Salts Change the pH -- 7.16.Log C-pH Diagrams -- 7.17.Exact pH Calculators -- ch. 8 Acid-Base Titrations -- 8.1.Strong Acid versus Strong Base-The Easy Titrations -- 8.2.The Charge Balance Method-An Excel Exercise for the Titration of a Strong Acid and a Strong Base -- 8.3.Detection of the End Point: Indicators -- 8.4.Standard Acid and Base Solutions -- 8.5.Weak Acid versus Strong Base-A Bit Less Straightforward -- 8.6.Weak Base versus Strong Acid -- 8.7.Titration of Sodium Carbonate-A Diprotic Base -- 8.8.Using a Spreadsheet to Perform the Sodium Carbonate-HC1 Titration -- 8.9.Titration of Polyprotic Acids -- 8.10.Mixtures of Acids or Bases -- 8.11.Equivalence Points from Derivatives of a Titration Curve -- 8.12.Titration of Amino Acids-They Are Acids and Bases -- 8.13.Kjeldahl Analysis: Protein Determination -- 8.14.Titrations Without Measuring Volumes -- |
|
Contents note continued: Experiment 17 Analysis of Commercial Hypochlorite or Peroxide Solution by Iodometric Titration -- Experiment 18 Iodometric Determination of Copper -- Experiment 19 Determination of Antimony by Titration with Iodine -- Experiment 20 Microscale Quantitative Analysis of Hard-Water Samples Using an Indirect Potassium Permanganate Redox Titration -- Potentiometric Titrations -- Experiment 21 pH Titration of Unknown Soda Ash -- Experiment 22 Potentiometric Titration of a Mixture of Chloride and Iodide -- Spectrochemical Measurements -- Experiment 23 Spectrophotometric Determination of Iron -- Experiment 24 Spectrophotometric Determination of Iron in Vitamin Tablets Using a 96 Well Plate Reader -- Experiment 25 Determination of Nitrate Nitrogen in Water -- Experiment 26 Spectrophotometric Determination of Lead on Leaves Using Solvent Extraction -- Experiment 27 Spectrophotometric Determination of Inorganic Phosphorus in Serum -- |
|
Contents note continued: Experiment 28 Spectrophotometric Determination of Manganese and Chromium in Mixture -- Experiment 29 Spectrophotometric Determination of Manganese in Steel Using a 96 Well Plate Reader -- Experiment 30 Ultraviolet Spectrophotometric Determination of Aspirin, Phenacetin, and Caffeine in APC Tablets Using Solvent Extraction -- Experiment 31 Infrared Determination of a Mixture of Xylene Isomers -- Experiment 32 Fluorometric Determination of Riboflavin (Vitamin B2) -- Atomic Spectrometry Measurements -- Experiment 33 Determination of Calcium by Atomic Absorption Spectrophotometry -- Experiment 34 Flame Emission Spectrometric Determination of Sodium -- Solid-Phase Extraction and Chromatography -- Experiment 35 Solid-Phase Extraction with Preconcentration, Elution, and Spectrophotometric Analysis -- Experiment 36 Thin-Layer Chromatography Separation of Amino Acids -- Experiment 37 Gas Chromatographic Analysis of a Tertiary Mixture -- |
|
Contents note continued: Experiment 38 Qualitative and Quantitative Analysis of Fruit Juices for Vitamin C Using High-Performance Liquid Chromatography -- Experiment 39 Analysis of Analgesics Using High-Performance Liquid Chromatography -- Mass Spectrometry -- Experiment 40 Capillary Gas Chromatography-Mass Spectrometry -- Hinetic Analysis -- Experiment 41 Enzymatic Determination of Glucose in Blood -- Flow Injection Analysis -- Experiment 42 Characterization of Physical Parameters of a Flow Injection Analysis System -- Experiment 43 Single-Line FIA: Spectrophotometric Determination of Chloride -- Experiment 44 Three-Line FIA: Spectrophotometric Determination of Phosphate -- Team Experiments -- Experiment 45 Method Validation and Quality Control Study -- Experiment 46 Proficiency Testing: Determination of z Values of Class Experiments |
|
Contents note continued: Experiment 7 Determination of Replaceable Hydrogen in Acid by Titration with Sodium Hydroxide -- Experiment 8 Determination of Total Alkalinity of Soda Ash -- Experiment 9 Determination of Aspirin Using Back Titration -- Experiment 10 Determination of Hydrogen Carbonate in Blood Using Back-Titration -- Complexometric Titration -- Experiment 11 Determination of Water Hardness with EDTA -- Precipitation Titrations -- Experiment 12 Determination of Silver in an Alloy: Volhard's Method -- Experiment 13 Determination of Chloride in a Soluble Chloride: Fajans' Method -- Potentiometric Measurements -- Experiment 14 Determination of the pH of Hair Shampoos -- Experiment 15 Potentiometric Determination of Fluoride in Drinking Water Using a Fluoride Ion-Selective Electrode -- Reduction-Oxidation Titrations -- Experiment 16 Analysis of an Iron Alloy or Ore by Titration with Potassium Dichromate -- |
|
Contents note continued: ch. 3 Statistics and Data Handling in Analytical Chemistry -- 3.1.Accuracy and Precision: There Is a Difference -- 3.2.Determinate Errors-They Are Systematic -- 3.3.Indeterminate Errors-They Are Random -- 3.4.Significant Figures: How Many Numbers Do You Need? -- 3.5.Rounding Off -- 3.6.Ways of Expressing Accuracy -- 3.7.Standard Deviation-The Most Important Statistic -- 3.8.Propagation of Errors-Not Just Additive -- 3.9.Significant Figures and Propagation of Error -- 3.10.Control Charts -- 3.11.The Confidence Limit-How Sure Are You? -- 3.12.Tests of Significance-Is There a Difference? -- 3.13.Rejection of a Result: The Q Test -- 3.14.Statistics for Small Data Sets -- 3.15.Linear Least Squares-How to Plot the Right Straight Line -- 3.16.Correlation Coefficient and Coefficient of Determination -- 3.17.Detection Limits-There Is No Such Thing as Zero -- 3.18.Statistics of Sampling-How Many Samples, How Large? -- 3.19.Powering a Study: Power Analysis -- |
|
Contents note continued: ch. 9 Complexometric Reactions and Titrations -- 9.1.Complexes and Formation Constants-How Stable Are Complexes? -- 9.2.Chelates: EDTA-The Ultimate Titrating Agent for Metals -- 9.3.Metal-EDTA Titration Curves -- 9.4.Detection of the End Point: Indicators-They Are Also Chelating Agents -- 9.5.Other Uses of Complexes -- 9.6.Cumulative Formation Constants β and Concentrations of Specific Species in Stepwise Formed Complexes -- ch. 10 Gravimetric Analysis and Precipitation Equilibria -- 10.1.How to Perform a Successful Gravimetric Analysis -- 10.2.Gravimetric Calculations-How Much Analyte Is There? -- 10.3.Examples of Gravimetric Analysis -- 10.4.Organic Precipitates -- 10.5.Precipitation Equilibria: The Solubility Product -- 10.6.Diverse Ion Effect on Solubility: Ksp and Activity Coefficients -- ch. 11 Precipitation Reactions and Titrations -- 11.1.Effect of Acidity on Solubility of Precipitates: Conditional Solubility Product -- |
|
Contents note continued: ch. G Century of the Gene-Genomics and Proteomics: DNA Sequencing and Protein Profiling -- G.1.Of What Are We Made? -- G.2.What Is DNA? -- G.3.Human Genome Project -- G.4.How Are Genes Sequenced? -- G.5.Replicating DNA: The Polymerase Chain Reaction -- G.6.Plasmids and Bacterial Artificial Chromosomes (BACs) -- G.7.DNA Sequencing -- G.8.Whole Genome Shotgun Sequencing -- G.9.Single-Nucleotide Polymorphisms -- G.10.DNA Chips -- G.11.Draft Genome -- G.12.Genomes and Proteomics: The Rest of the Story -- APPENDIX A LITERATURE OF ANALYTICAL CHEMISTRY -- APPENDIX B REVIEW OF MATHEMATICAL OPERATIONS: EXPONENTS, LOGARITHMS, AND THE QUADRATIC FORMULA -- APPENDIX C TABLES OF CONSTANTS -- Table C.1 Dissociation Constants for Acids -- Table C.2a Dissociation Constants for Basic Species -- Table C.2b Acid Dissociation Constants for Basic Species -- Table C.3 Solubility Product Constants -- Table C.4 Formation Constants for Some EDTA Metal Chelates -- |
|
Contents note continued: Table C.5 Some Standard and Formal Reduction Electrode Potentials -- Available on textbook website: www.wiley.com/college/christian -- APPENDIX D SAFETY IN THE LABORATORY -- Available on textbook website: www.wiley.com/college/christian -- APPENDIX E PERIODIC TABLES ON THE WEB -- APPENDIX F ANSWERS TO PROBLEMS -- Available on textbook website: www.wiley.com/college/christian -- Experiments -- Use of Apparatus -- Experiment 1 Use of the Analytical Balance -- Experiment 2 Use of the Pipet and Buret and Statistical Analysis -- Experiment 3 Analysis of Volumetric Measurements Using Spectrophotometric Microplate Readers and Spreadsheet Calculations -- Gravimetry -- Experiment 4 Gravimetric Determination of Chloride -- Experiment 5 Gravimetric Determination of SO3 in a Soluble Sulfate -- Experiment 6 Gravimetric Determination of Nickel in a Nichrome Alloy -- Acid-Base Titrations -- |
|
Machine generated contents note: ch. 1 Analytical Objectives, or: What Analytical Chemists Do -- 1.1.What Is Analytical Science? -- 1.2.Qualitative and Quantitative Analysis: What Does Each Tell Us? -- 1.3.Getting Started: The Analytical Process -- 1.4.Validation of a Method-You Have to Prove It Works! -- 1.5.Analyze Versus Determine-They Are Different -- 1.6.Some Useful Websites -- ch. 2 Basic Tools and Operations of Analytical Chemistry -- 2.1.The Laboratory Notebook-Your Critical Record -- 2.2.Laboratory Materials and Reagents -- 2.3.The Analytical Balance-The Indispensible Tool -- 2.4.Volumetric Glassware-Also Indispensible -- 2.5.Preparation of Standard Base Solutions -- 2.6.Preparation of Standard Acid Solutions -- 2.7.Other Apparatus-Handling and Treating Samples -- 2.8.Igniting Precipitates-Gravimetric Analysis -- 2.9.Obtaining the Sample-Is It Solid, Liquid, or Gas? -- 2.10.Operations of Drying and Preparing a Solution of the Analyte -- 2.11.Laboratory Safety -- |
| Summary |
"The 7th Edition of Gary Christian's Analytical Chemistry focuses on more in-depth coverage and information about Quantitative Analysis (aka Analytical Chemistry) and related fields. The content builds upon previous editions with more enhanced content that deals with principles and techniques of quantitative analysis with more examples of analytical techniques drawn from areas such as clinical chemistry, life sciences, air and water pollution, and industrial analyses"--Provided by publisher |
| Notes |
Includes index |
| Bibliography |
Includes bibliographical references and index |
| Subject |
Chemistry -- Textbooks.
|
|
Chemistry, Analytic -- Textbooks.
|
|
Chemistry, Analytic -- Quantitative -- Textbooks.
|
|
Chemistry, Analytic -- Quantitative.
|
| Reading List |
SLE213 prescribed text 2024
|
|
SLE316 prescribed text 2024
|
| Genre/Form |
Textbooks.
|
| Author |
Dasgupta, Purnendu, author
|
|
Schug, Kevin, author
|
| LC no. |
2013019926 |
| ISBN |
0470887575 (hardback : acid-free paper) |
|
9780470887578 (hardback : acid-free paper) |
