| Description |
1 online resource (ix, 248 pages) : illustrations |
| Series |
Catalysis by metal complexes ; v. 30 |
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Catalysis by metal complexes ; v. 30.
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| Contents |
Cover -- TABLE OF CONTENTS -- CHAPTER 1 HOMOGENEOUS CATALYSIS -- ADVANTAGES AND PROBLEMS -- 1.1 Catalysis -- 1.2 Catalyst Stability -- 1.2.1 THERMALLY INDUCED DECOMPOSITION -- 1.2.2 CHEMICALLY INDUCED DECOMPOSITION -- 1.2.3 PHYSICAL LOSS FROM THE PROCESS -- 1.3 Layout of the Book -- 1.4 References -- CHAPTER 2 CLASSICAL HOMOGENEOUS CATALYST SEPARATION TECHNOLOGY -- 2.1.1 Coverage of Chapter -- 2.2 General Process Considerations -- 2.3 Everything is a Reactor -- 2.4 Overview of Separation Technologies -- 2.4.1 TRADITIONAL COBALT WITH CATALYST DECOMPOSITION -- 2.4.2 UNION CARBIDE-DAVY GAS RECYCLE PROCESS -- 2.4.3 LIQUID RECYCLE -- 2.4.4 BIPHASIC SYSTEMS; WATER-ORGANIC -- 2.4.5 INDUCED PHASE SEPARATION -- 2.4.6 NON-AQUEOUS PHASE SEPARATION -- 2.5 Hypothetical processes -- How Might the Product be Separated from the Catalyst? -- 2.5.1 PROPENE HYDROFORMYLATION -- 2.5.2 1-OCTENE HYDROFORMYLATION -- 2.5.3 ALLYL ALCOHOL -- 2.5.4 METHOXYVINYLNAPHTHALENE -- 2.5.5 SEPARATION TECHNOLOGY FOR LESS STABLE CATALYSTS -- 2.6 Real-World Complications -- 2.6.1 ORGANOPHOSPHORUS LIGAND DEGRADATIONS -- 2.6.2 SEPARATING BYPRODUCTS FROM REACTANTS OR PRODUCTS -- 2.6.3 INTRINSIC CATALYST DEACTIVATION -- 2.7 Further Separation Challenges -- 2.7.1 RECOVERY OF METAL VALUES FROM A SPENT CATALYST -- 2.8 Concluding Remarks -- 2.9 References -- CHAPTER 3 SUPPORTED CATALYSTS -- 3.1 Introduction -- 3.2 Short Historical Overview -- 3.3 Polystyrene Supported Catalysts -- 3.4 Silica Supported Catalyst -- 3.5 Catalysis in Interphases -- 3.6 Ordered Mesoporous Support -- 3.7 Non-covalently Supported Catalysts -- 3.8 Supported Aqueous Phase Catalysis -- 3.9 Process Design [71] -- 3.10 Concluding Remarks -- 3.11 References -- CHAPTER 4 SEPARATION BY SIZE-EXCLUSION FILTRATION -- 4.1 Introduction -- 4.2 Reactors -- 4.2.1 DEAD-END FILTRATION REACTORS -- 4.2.2 CROSS-FLOW FILTRATION REACTORS -- 4.3 Membranes -- 4.3.1 CLASSIFICATION OF FILTRATION TYPES -- 4.3.2 MEMBRANE MATERIALS -- 4.4 Dendrimer Supported Catalysts -- 4.4.1 KHARASCH ADDITION REACTION -- 4.4.2 ALLYLIC SUBSTITUTION REACTIONS -- 4.4.3 HYDROVINYLATION REACTION -- 4.4.4 HYDROGENATION REACTION -- 4.4.5 MICHAEL ADDITION REACTION -- 4.5 Dendritic Effects -- 4.6 Unmodified or Non-dendritic Catalysts -- 4.6.1 HYDROGENATION -- 4.6.2 PHASE TRANSFER CATALYSIS -- 4.7 Soluble Polymer Supported Catalysts -- 4.8 Concluding Remarks -- 4.9 References -- CHAPTER 5 BIPHASIC SYSTEMS: WATER -- ORGANIC -- 5.1 Introduction -- 5.2 Immobilization with the Help of Liquid Supports -- 5.2.1 GENERAL -- 5.2.2 BIPHASIC SYSTEMS -- 5.2.3 AQUEOUS BIPHASIC CATALYSIS -- 5.2.4 EXAMPLES OF AQUEOUS BIPHASIC CATALYSIS --tidtid634 |
| Summary |
"This book looks at new ways of tackling the problem of separating reaction products from homogeneous catalytic solutions. The new processes involve low leaching supported catalysts, soluble supports such as polymers and dendrimers and unusual solvents such as water, fluorinated organics, ionic liquids and supercritical fluids. The advantages of the different possibilities are discussed alongside suggestions for further research that will be required for commercialisation. Unlike other books, in addition to the chemistry involved, the book looks at the process design that would be required to bring the new approaches to fruition. Comparisons are given with existing processes that have already been successfully applied and examples are given where these approaches are not suitable." "This book is an invaluable resource for industrialists in the chemical and pharmaceutical industries, particularly those involved with improving environmental impact of current or future processes. It is also a useful resource for academics who wish to apply homogeneous catalysis to solving real problems and for advanced undergraduate and postgraduate courses in catalysis."--Jacket |
| Analysis |
chemie |
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chemistry |
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katalyse |
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catalysis |
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chemische proceskunde |
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chemical engineering |
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organische scheikunde |
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organic chemistry |
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Chemistry (General) |
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Chemie (algemeen) |
| Bibliography |
Includes bibliographical references |
| Notes |
Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002. http://purl.oclc.org/DLF/benchrepro0212 MiAaHDL |
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Print version record |
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digitized 2010 HathiTrust Digital Library committed to preserve pda MiAaHDL |
| Subject |
Chemical processes.
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TECHNOLOGY & ENGINEERING -- Chemical & Biochemical.
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SCIENCE -- Chemistry -- Industrial & Technical.
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Chemical processes.
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Chimie.
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Science des matériaux.
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Chemical processes
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Katalysator
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Organische Synthese
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Recycling
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| Form |
Electronic book
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| Author |
Cole-Hamilton, D. J. (David John)
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Tooze, Robert P
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| ISBN |
9781402040870 |
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1402040873 |
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1402040865 |
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9781402040863 |
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6610634637 |
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9786610634637 |
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